LiCl-Promoted Chain Growth Kumada Catalyst-Transfer Polycondensation of the "Reversed" Thiophene Monomer
文献类型：期刊论文
| 作者 | Wu SP ; Huang L ; Tian HK ; Geng YH ; Wang FS |
| 刊名 | macromolecules
 |
| 出版日期 | 2011 |
| 卷号 | 44期号:19页码:7558-7567 |
| 关键词 | END-GROUP-FUNCTIONALIZATION GRIGNARD METATHESIS METHOD REGIOREGULAR POLY(3-HEXYLTHIOPHENE) BLOCK-COPOLYMERS MOLECULAR-WEIGHT CONDENSATION POLYMERIZATION MICROPHASE SEPARATION LIVING POLYMERIZATION CONJUGATED POLYMERS UNIVERSAL METHOD |
| ISSN号 | 0024-9297 |
| 通讯作者 | geng yh |
| 中文摘要 | the effect of licl on the chain growth kumada catalyst-transfer polycondensation (kctp) of the "reversed" thiophene monomer, 5-bromo-2-chloromagnesio-3-hexylthiophene (3a) (that has bulky substituent adjacent to the chloromagnesium group), was investigated. licl promotes the polymerization of 3a, and the polymerization also exhibits living characteristics similar to those of the "normal" monomer, 2-bromo-5-chloromagnesio-3-heacylthiophene (3b). however, initiation is much slower than chain propagation due to the steric hindrance between hexyl groups in the transmetalation (tm) step that leads to the formation of the initiator via head-to-head (hh) coupling. consequently, regioregular poly(3-hexylthiophene) (p3ht) with large polydispersity (pdi) and higher number-average molecular weight (m(n)) than the theoretical value was obtained. because of the slow initiation with 3a, the polymerization of 3a occurs primarily after the consumption of 3b in the copolymerization of 3a and 3b, and p3ht with high regioregularity was still obtained. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000295487600009 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44291]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wu SP,Huang L,Tian HK,et al. LiCl-Promoted Chain Growth Kumada Catalyst-Transfer Polycondensation of the "Reversed" Thiophene Monomer[J]. macromolecules,2011,44(19):7558-7567. |
| APA | Wu SP,Huang L,Tian HK,Geng YH,&Wang FS.(2011).LiCl-Promoted Chain Growth Kumada Catalyst-Transfer Polycondensation of the "Reversed" Thiophene Monomer.macromolecules,44(19),7558-7567. |
| MLA | Wu SP,et al."LiCl-Promoted Chain Growth Kumada Catalyst-Transfer Polycondensation of the "Reversed" Thiophene Monomer".macromolecules 44.19(2011):7558-7567. |
入库方式： OAI收割
来源：长春应用化学研究所
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