Relationship between Structural Gel and Mechanical Gel for ABA Triblock Copolymer in Solutions: A Molecular Dynamics Simulation
文献类型：期刊论文
| 作者 | Fu CL ; Sun ZY ; An LJ |
| 刊名 | journal of physical chemistry b
 |
| 出版日期 | 2011 |
| 卷号 | 115期号:39页码:11345-11351 |
| 关键词 | THERMOREVERSIBLE GELS 1 BLOCK-COPOLYMER 2-BUTYLENE OXIDE ETHYLENE-OXIDE GELATION TRANSITION MICELLIZATION POLYMERS SOLVENT SYSTEMS |
| ISSN号 | 1520-6106 |
| 通讯作者 | sun zy |
| 中文摘要 | polymer gel exists ubiquitously in our daily life, as in food, cosmetics, drugs, and so on. from the structural point of view, the 3d network can be found in a structural gel. in most experimental work, the gel is identified by the sharp increase in modules; that is, the gel should have similar properties as those of a solid, which is named as mechanical gel. however, not all structural gels have strong mechanical responses. therefore, studying the relationship between structural gel and mechanical gel is very important. in this work, we investigate the structure and mechanical properties of symmetric aba copolymers with solvophobic end blocks during the sol-gel transition. three typical systems with weak, middle, and strong solvophobicities are simulated. it is found that the gelation concentration, gel structure, and mechanical response of structural gel are strongly affected by the solvophobicity of aba block copolymer. we also find that only the gel formed in strong solvophobic systems has a strong mechanical response. furthermore, the influence of solvophobicity of a-block on the static and dynamic properties of aba block copolymers in solutions is also studied to give a molecular understanding of physical gelation. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000295245400004 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44297]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Fu CL,Sun ZY,An LJ. Relationship between Structural Gel and Mechanical Gel for ABA Triblock Copolymer in Solutions: A Molecular Dynamics Simulation[J]. journal of physical chemistry b,2011,115(39):11345-11351. |
| APA | Fu CL,Sun ZY,&An LJ.(2011).Relationship between Structural Gel and Mechanical Gel for ABA Triblock Copolymer in Solutions: A Molecular Dynamics Simulation.journal of physical chemistry b,115(39),11345-11351. |
| MLA | Fu CL,et al."Relationship between Structural Gel and Mechanical Gel for ABA Triblock Copolymer in Solutions: A Molecular Dynamics Simulation".journal of physical chemistry b 115.39(2011):11345-11351. |
入库方式： OAI收割
来源：长春应用化学研究所
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