Lipase/esterase-catalyzed ring-opening polymerization: A green polyester synthesis technique
文献类型：期刊论文
| 作者 | Yang Y ; Yu Y ; Zhang YX ; Liu CB ; Shi W ; Li QS |
| 刊名 | process biochemistry
 |
| 出版日期 | 2011 |
| 卷号 | 46期号:10页码:1900-1908 |
| 关键词 | ANTARCTICA-LIPASE-B SUPERCRITICAL CARBON-DIOXIDE WHOLE-CELL BIOCATALYST EPSILON-CAPROLACTONE TRIMETHYLENE CARBONATE ENZYMATIC-SYNTHESIS MOLECULAR-WEIGHT OMEGA-PENTADECALACTONE IMMOBILIZED LIPASE BLOCK-COPOLYMERS |
| ISSN号 | 1359-5113 |
| 通讯作者 | li qs |
| 中文摘要 | in the last decade, there has been increased interest in lipase/esterase-catalyzed ring-opening polymerization as an alternative to metal-based catalytic processes. this review focuses on three components in the reaction system, namely biocatalysts, reaction medium and monomers. novel lipases or esterases are described with particular emphasis on, those derived from thermophiles, immobilized enzymes and recombinant whole-cell biocatalysts. green solvents in enzymatic ring-opening polymerization, including water, ionic liquids, supercritical carbon dioxide and hydrofluorocarbon solvents, are also discussed. enzymatic ring-opening polymerization is reviewed with regard to the variety of polymers obtainable, such as polyesters, polycarbonates, polyphosphates and polythioesters. among these, enzymatic synthesis of polyesters has been most widely investigated, and is discussed for lactones with small to large ring sizes. finally, the mechanism of enzymatic ring-opening polymerization is described, which is generally accepted as a monomer-activated mechanism. overall, the review demonstrates that lipase/esterase-catalyzed synthesis of polymers via ring-opening polymerization provides an effective platform for conducting "green polymer chemistry". (c) 2011 elsevier ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000295913700002 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44320]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yang Y,Yu Y,Zhang YX,et al. Lipase/esterase-catalyzed ring-opening polymerization: A green polyester synthesis technique[J]. process biochemistry,2011,46(10):1900-1908. |
| APA | Yang Y,Yu Y,Zhang YX,Liu CB,Shi W,&Li QS.(2011).Lipase/esterase-catalyzed ring-opening polymerization: A green polyester synthesis technique.process biochemistry,46(10),1900-1908. |
| MLA | Yang Y,et al."Lipase/esterase-catalyzed ring-opening polymerization: A green polyester synthesis technique".process biochemistry 46.10(2011):1900-1908. |
入库方式： OAI收割
来源：长春应用化学研究所
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