ALTERNATING COPOLYMERIZATION OF CYCLOHEXENE OXIDE AND CARBON DIOXIDE UNDER COBALT PORPHYRIN CATALYST
文献类型：期刊论文
| 作者 | Qin YS ; Chen LJ ; Wang XH ; Zhao XJ ; Wang FS |
| 刊名 | chinese journal of polymer science
 |
| 出版日期 | 2011 |
| 卷号 | 29期号:5页码:602-608 |
| 关键词 | POLYCARBONATE SYNTHESIS POLYMER SYNTHESIS MOLECULAR-WEIGHT MILD CONDITIONS CO2 EPOXIDE COMPLEXES SALEN SYSTEM OPTIMIZATION |
| ISSN号 | 0256-7679 |
| 通讯作者 | wang xh |
| 中文摘要 | cobalt porphyrin complexes (tppco(iii)x) (tpp = 5,10,15,20-tetraphenyl-porphyrin; x = halide) in combination with bis(triphenylphosphine) iminium chloride (ppncl) were used for the copolymerization of cyclohexene oxide and co(2). the highest turnover frequency of 67.2 h(-1) was achieved after 13 h at 20 degrees c, and the obtained poly(1,2-cyclohexylene carbonate) (pchc) showed number average molecular weight (m(n)) of 10 x 10(3). though the obtained pchc showed atactic structure, the m-centered tetrads content reached 58.1% at co(2) pressure of 1.0 mpa, and decreased to 51.9% at co(2) pressure of 6.0 mpa, indicating that it was inclined to form atactic polymer at high co(2) pressure. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000297864600011 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44363]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qin YS,Chen LJ,Wang XH,et al. ALTERNATING COPOLYMERIZATION OF CYCLOHEXENE OXIDE AND CARBON DIOXIDE UNDER COBALT PORPHYRIN CATALYST[J]. chinese journal of polymer science,2011,29(5):602-608. |
| APA | Qin YS,Chen LJ,Wang XH,Zhao XJ,&Wang FS.(2011).ALTERNATING COPOLYMERIZATION OF CYCLOHEXENE OXIDE AND CARBON DIOXIDE UNDER COBALT PORPHYRIN CATALYST.chinese journal of polymer science,29(5),602-608. |
| MLA | Qin YS,et al."ALTERNATING COPOLYMERIZATION OF CYCLOHEXENE OXIDE AND CARBON DIOXIDE UNDER COBALT PORPHYRIN CATALYST".chinese journal of polymer science 29.5(2011):602-608. |
入库方式： OAI收割
来源：长春应用化学研究所
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