中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A facile route to hollow microspherical polyaniline

文献类型:期刊论文

作者Zhang HM ; Li YP ; Wang XH ; Li J ; Wang FS
刊名polymer
出版日期2011
卷号52期号:19页码:4246-4252
关键词ACID DOPED POLYANILINE CONDUCTING-POLYMER ELECTRICAL-CONDUCTIVITY AQUEOUS DISPERSION ANILINE OLIGOMERS METALLIC REGIME EMERALDINE BASE SPHERES NANOTUBES TEMPLATE
ISSN号0032-3861
通讯作者wang xh
中文摘要a facile method to prepare polyaniline hollow microsphere was developed using potassium hexacyanoferrate (iii) as oxidant for polymerization of aniline in aqueous condition without acid or alkali or organic solvent, and doped polyaniline with electrical conductivity of ca. 10(-3) s/cm was directly obtained with hexacyanoferrate (ii) anion surrounding imine and amine atoms in polyaniline backbone, which was seven orders of magnitude higher than that of polyaniline hollow spheres synthesized in alkaline medium (ca. 10(-10) s/cm). the hollow spherical structure was formed by a self-assembly process of spherical aniline micelles as shell and inner aniline droplet as core, and nanoscale polydispersed hollow spheres whose diameter varied from 380 nm to 700 nm with a shell thickness from 50 nm to 78 nm were readily obtained. (c) 2011 elsevier ltd. all rights reserved.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000294796300010
公开日期2012-06-08
源URL[http://ir.ciac.jl.cn/handle/322003/44374]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Zhang HM,Li YP,Wang XH,et al. A facile route to hollow microspherical polyaniline[J]. polymer,2011,52(19):4246-4252.
APA Zhang HM,Li YP,Wang XH,Li J,&Wang FS.(2011).A facile route to hollow microspherical polyaniline.polymer,52(19),4246-4252.
MLA Zhang HM,et al."A facile route to hollow microspherical polyaniline".polymer 52.19(2011):4246-4252.

入库方式: OAI收割

来源:长春应用化学研究所

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