Formation of Singly Bonded PhCH(2)C(60)-C(60)CH(2)Ph Dimers from 1,2-(PhCH(2))HC(60) via Electroreductive C(60)-H Activation
文献类型：期刊论文
| 作者 | Yang WW ; Li ZJ ; Gao X |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 76期号:15页码:6067-6074 |
| 关键词 | X-RAY-STRUCTURE FULLERENE CHEMISTRY MOLECULAR ELECTRONICS SHAPED C-120 SOLAR-CELLS DERIVATIVES REAGENTS C-60(2-) C60H2 1ST |
| ISSN号 | 0022-3263 |
| 通讯作者 | gao x |
| 中文摘要 | singly bonded phch(2)c(60)-c(60)ch(2)ph dimers are generated via controlled-potential bulk electroreduction and electrooxidation of 1,2-(phch(2))hc(60). the reaction mixture was purified by hplc, and the isolated fraction was characterized with single-crystal x-ray diffractions, (1)h and (13)nmr, ms, elemental analysis, and cyclic voltammetry. it was shown that the fraction consists of two hplc-inseparable phch(2)c(60)-c(60)ch(2)ph regioisomers, which are assigned as the meso and racemic regioisomers. the bulk electrolysis processes for the formation of the dimers were followed by in situ cyclic voltammetry and were further corroborated with an in situ voltammetric titration of 1,2-(phch(2))hc(60) with tetra-n-butylammonium hydroxide (tbaoh), on the basis of which a reaction mechanism is proposed. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44414]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yang WW,Li ZJ,Gao X. Formation of Singly Bonded PhCH(2)C(60)-C(60)CH(2)Ph Dimers from 1,2-(PhCH(2))HC(60) via Electroreductive C(60)-H Activation[J]. journal of organic chemistry,2011,76(15):6067-6074. |
| APA | Yang WW,Li ZJ,&Gao X.(2011).Formation of Singly Bonded PhCH(2)C(60)-C(60)CH(2)Ph Dimers from 1,2-(PhCH(2))HC(60) via Electroreductive C(60)-H Activation.journal of organic chemistry,76(15),6067-6074. |
| MLA | Yang WW,et al."Formation of Singly Bonded PhCH(2)C(60)-C(60)CH(2)Ph Dimers from 1,2-(PhCH(2))HC(60) via Electroreductive C(60)-H Activation".journal of organic chemistry 76.15(2011):6067-6074. |
入库方式： OAI收割
来源：长春应用化学研究所
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