Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects
文献类型：期刊论文
| 作者 | Nomura K ; Liu JY |
| 刊名 | dalton transactions
 |
| 出版日期 | 2011 |
| 卷号 | 40期号:30页码:7666-7682 |
| 关键词 | SYNDIOSPECIFIC STYRENE POLYMERIZATION MAO CATALYST SYSTEMS ZIEGLER-NATTA CATALYSTS ANCILLARY DONOR LIGANDS ETHYLENE POLYMERIZATION METALLOCENE CATALYSTS (CYCLOPENTADIENYL)(ARYLOXY)TITANIUM(IV) COMPLEXES STRUCTURAL-ANALYSIS KETIMIDE COMPLEXES COCATALYST SYSTEMS |
| ISSN号 | 1477-9226 |
| 通讯作者 | nomura k |
| 中文摘要 | selected examples concerning effects of both cyclopentadienyl fragment (cp') and anionic donor ligand (y) in nonbridged modified half-titanocenes of the type, cp'tix(2)(y) (x = halogen, alkyl), as new type of olefin polymerisation catalysts have been reviewed. these complexes displayed unique characteristics not only for ethylene (co) polymerisation but also for syndiospecific styrene polymerisation, ethylene/styrene copolymerisation; precise fine tuning of the ligand substituents plays an important role for the successful (co) polymerisation; a different mechanistic consideration for the syndiospecific styrene polymerisation, which can explain the copolymerisation behaviour in this catalysis, has also been introduced. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000292972000002 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44444]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Nomura K,Liu JY. Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects[J]. dalton transactions,2011,40(30):7666-7682. |
| APA | Nomura K,&Liu JY.(2011).Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects.dalton transactions,40(30),7666-7682. |
| MLA | Nomura K,et al."Half-titanocenes for precise olefin polymerisation: effects of ligand substituents and some mechanistic aspects".dalton transactions 40.30(2011):7666-7682. |
入库方式： OAI收割
来源：长春应用化学研究所
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