Probing Dye-Correlated Interplay of Energetics and Kinetics in Mesoscopic Titania Solar Cells with 4-tert-Butylpyridine
文献类型：期刊论文
| 作者 | Long HJ ; Zhou DF ; Zhang M ; Peng CY ; Uchida S ; Wang P |
| 刊名 | journal of physical chemistry c
 |
| 出版日期 | 2011 |
| 卷号 | 115期号:29页码:14408-14414 |
| 关键词 | PHOTOINDUCED ELECTRON INJECTION NANOCRYSTALLINE THIN-FILMS FREE ORGANIC-DYES CHARGE RECOMBINATION CONVERSION-EFFICIENCY HIGHLY EFFICIENT SURFACE-STATES DIOXIDE FILMS COUMARIN DYES TIO2 FILMS |
| ISSN号 | 1932-7447 |
| 通讯作者 | wang p |
| 中文摘要 | the adsorption of 4-tert-butylpyridine (tbp) on the surface of oxide semiconductors can tune their interband state distributions as well as the conduction band edges, offering a straightforward tactic to modulate the energy alignments at the titania/dye/electrolyte interface in dye-sensitized solar cells. in this work, by stepwise augmenting the tbp concentration in electrolytes, we investigate the energetic and kinetic interplays in mesoscopic titania solar cells based upon two push pull organic dyes c218 and d205. tbp at a higher concentration, while better retarding triiodide interception of photoinjected electrons in c218 cells, has strikingly induced an acceleration of interfacial charge recombination with triiodide in devices employing the d205 dye, accounting for a much smaller photovoltage enhancement with respect to the c218 counterpart. transient emission measurements disclose that the exciton dissociation at the titania/c218 dye interface does not noticeably vary despite a tbp-correlated conduction band edge elevation, which has otherwise prompted an evident gibbs free-energy-dependent rate of electron injection in cells based on the d205 photosensitizer. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000292892500056 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44453]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Long HJ,Zhou DF,Zhang M,et al. Probing Dye-Correlated Interplay of Energetics and Kinetics in Mesoscopic Titania Solar Cells with 4-tert-Butylpyridine[J]. journal of physical chemistry c,2011,115(29):14408-14414. |
| APA | Long HJ,Zhou DF,Zhang M,Peng CY,Uchida S,&Wang P.(2011).Probing Dye-Correlated Interplay of Energetics and Kinetics in Mesoscopic Titania Solar Cells with 4-tert-Butylpyridine.journal of physical chemistry c,115(29),14408-14414. |
| MLA | Long HJ,et al."Probing Dye-Correlated Interplay of Energetics and Kinetics in Mesoscopic Titania Solar Cells with 4-tert-Butylpyridine".journal of physical chemistry c 115.29(2011):14408-14414. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。