Facile Functionalization of Polyethylene via Click Chemistry
文献类型：期刊论文
| 作者 | Hong M ; Liu JY ; Li BX ; Li YS |
| 刊名 | macromolecules
 |
| 出版日期 | 2011 |
| 卷号 | 44期号:14页码:5659-5665 |
| 关键词 | LIVING RADICAL POLYMERIZATION REPEATED 1 PALLADIUM-CATALYZED COPOLYMERIZATION 2-INSERTION TRANSITION-METAL-COMPLEXES REGIOSELECTIVE COPOLYMERIZATION TITANIUM COMPLEXES MATERIALS SCIENCE BLOCK-COPOLYMERS CHELATE LIGANDS POLAR MONOMERS |
| ISSN号 | 0024-9297 |
| 通讯作者 | li ys |
| 中文摘要 | a series of well-defined functional polyethylene graft copolymers with high molecular weights have been conveniently synthesized via the combination of ethylene/5-norbornene-2-methyl propargyl ether (nmpe) copolymerization using bis(beta-enaminoketonato)titanium catalysts and following click coupling reaction. bis(beta-enaminoketonato)titanium catalysts have been proved to be the potent catalysts for ethylene/nmpe copolymerization, producing high molecular weight copolymers with unimodal molecular weight distributions. (13)c nmr (dept) and (1)h nmr spectra reveal the copolymerization proceeds in a regioselective way with allcynyl group retained near the main chain. the following click coupling reactions between ethylene/nmpe copolymer and azido-terminated polymer (peo-n(3), ps-n(3)) have been achieved under mild conditions independent of the chemical structure and molecular weight of azido-terminated polymer, providing functional polyethylene with well-defined structure and high molecular weight. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000292850100016 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44455]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Hong M,Liu JY,Li BX,et al. Facile Functionalization of Polyethylene via Click Chemistry[J]. macromolecules,2011,44(14):5659-5665. |
| APA | Hong M,Liu JY,Li BX,&Li YS.(2011).Facile Functionalization of Polyethylene via Click Chemistry.macromolecules,44(14),5659-5665. |
| MLA | Hong M,et al."Facile Functionalization of Polyethylene via Click Chemistry".macromolecules 44.14(2011):5659-5665. |
入库方式： OAI收割
来源：长春应用化学研究所
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