Three azido-, alk/phenoxido- and acetato-bridged tetranuclear nickel complexes featuring defective double-cubane
文献类型：期刊论文
| 作者 | Lin SY ; Xu GF ; Zhao L ; Guo YN ; Tang JK ; Wang QL ; Liu GX |
| 刊名 | inorganica chimica acta
 |
| 出版日期 | 2011 |
| 卷号 | 373期号:1页码:173-178 |
| 关键词 | MAGNETIC-PROPERTIES METAL-COMPLEXES SINGLE-CRYSTAL GROUND-STATE SCHIFF-BASE DFT METHODS CLUSTER WATER RELAXATION HONEYCOMB |
| ISSN号 | 0020-1693 |
| 通讯作者 | tang jk |
| 中文摘要 | three new tetranuclear nickel(ii) complexes of general formula [ni(4)(l)(2)(n(3))(2)(ch(3)coo)(2)(ch(3)o)(2)](2)center dot xch(3)oh center dot yh(2)o (hl = hl(1), hl(2) and hl(3); x = 0, y = 1 for 1; x = 2, y = 0 for 2 and x = 2, y = 4 for 3) were synthesized and characterized by single crystal x-ray diffraction and magnetic measurements. single crystal x-ray studies reveal that all three complexes exhibit similar tetranuclear face-shared defective double-cubane structure, having azido-, alk/phenoxido- and acetato-bridges. magnetic susceptibility measurements on the complexes in the range of 300-2 k indicate ferromagnetic coupling between the metal ions. the slightly different magnetic behaviors observed are probably caused by subtle structural differences between the respective [ni(4)o(4)n(2)] cores induced by ligand variation. (c) 2011 elsevier b. v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000291244600025 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44470]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lin SY,Xu GF,Zhao L,et al. Three azido-, alk/phenoxido- and acetato-bridged tetranuclear nickel complexes featuring defective double-cubane[J]. inorganica chimica acta,2011,373(1):173-178. |
| APA | Lin SY.,Xu GF.,Zhao L.,Guo YN.,Tang JK.,...&Liu GX.(2011).Three azido-, alk/phenoxido- and acetato-bridged tetranuclear nickel complexes featuring defective double-cubane.inorganica chimica acta,373(1),173-178. |
| MLA | Lin SY,et al."Three azido-, alk/phenoxido- and acetato-bridged tetranuclear nickel complexes featuring defective double-cubane".inorganica chimica acta 373.1(2011):173-178. |
入库方式： OAI收割
来源：长春应用化学研究所
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