Conjugated Polymers Based on a S- and N-Containing Heteroarene: Synthesis, Characterization, and Semiconducting Properties
文献类型:期刊论文
作者 | Chen YG ; Tian HK ; Yan DH ; Geng YH ; Wang FS |
刊名 | macromolecules
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出版日期 | 2011 |
卷号 | 44期号:13页码:5178-5185 |
关键词 | THIN-FILM TRANSISTORS FIELD-EFFECT TRANSISTORS HIGH-PERFORMANCE HIGH-MOBILITY COPOLYMERS POLYTHIOPHENES STABILITY TRANSPORT |
ISSN号 | 0024-9297 |
通讯作者 | geng yh |
中文摘要 | three alternating conjugated polymers (p-btc10, p-btc12, and p-btc16) comprising a novel s- and n-containing heteroarene, i.e., n-dodecyldithieno[2,3-b;7,6-b]carbazole, and 4,4'-dialkyl-2,2'-bithiophenes have been designed and synthesized. the nitrogen atom in the heteroarene allows introducing an additional alkyl substituent in each repeating unit of the polymers. the resulting polymers are thermally stable with decomposition temperature of similar to 400 degrees c and highly soluble in various organic solvents, such as tetrahydrofuran (thf), toluene, chloroform, and chlorobenzene, etc. bottom gate, top contact otft devices were fabricated by solution casting. mobility of the devices increased with an increase of the alkyl chain length in bithiophene units, and p-btc10, p-btc12, and p-btc16 exhibited the mobilities up to 0.0064, 0.022, and 0.035 cm(2)/(v s), respectively. the mobility of p-btc16 is comparable to that of regioregular poly(3-hexylthiophene) (rr-p3ht) reference devices, indicating that this heteroarene is a potential building block for high-mobility conjugated polymers. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000292417800016 |
公开日期 | 2012-06-08 |
源URL | [http://ir.ciac.jl.cn/handle/322003/44480] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Chen YG,Tian HK,Yan DH,et al. Conjugated Polymers Based on a S- and N-Containing Heteroarene: Synthesis, Characterization, and Semiconducting Properties[J]. macromolecules,2011,44(13):5178-5185. |
APA | Chen YG,Tian HK,Yan DH,Geng YH,&Wang FS.(2011).Conjugated Polymers Based on a S- and N-Containing Heteroarene: Synthesis, Characterization, and Semiconducting Properties.macromolecules,44(13),5178-5185. |
MLA | Chen YG,et al."Conjugated Polymers Based on a S- and N-Containing Heteroarene: Synthesis, Characterization, and Semiconducting Properties".macromolecules 44.13(2011):5178-5185. |
入库方式: OAI收割
来源:长春应用化学研究所
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