Effect of Electrolyte on Electrocatalytic Performance of Carbon Supported Pd Catalyst for Formic Acid Oxidation
文献类型：期刊论文
| 作者 | Hong YJ ; Shen JZ ; Li HZ ; Tang YW ; Lu TH |
| 刊名 | chinese journal of inorganic chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 27期号:7页码:1383-1387 |
| 关键词 | FUEL-CELL ANODIC CATALYST ELECTROOXIDATION DECOMPOSITION BEHAVIOR |
| ISSN号 | 1001-4861 |
| 通讯作者 | lu th |
| 中文摘要 | in order to understand the effect of (nh(4))(2)so(4), k(2)so(4) and h(2)so(4) electrolytes on the electrocatalytic performance and the mechanisim of the pd/c catalyst electrode for formic acid oxidation, the performance of the said electrode for formic acid oxidation in different electrolytes were evaluated using electrochemical methods. the results show that the electrocatalytic activity and stability are decreased according to the following order: (nh(4))(2)so(4)>. k(2)so(4)>h(2)so(4). because of the existence of formic acid, the difference in the ph value of different electrolytes is small. thus, the effect of the ph value of the electrolytes is small. moreover, the conductivity of the electrolytes would affect the peak potential of the formic acid oxidation. finally, nh(4)(+) plays a special rule. it could decrease the amount of co adsorbed on the pd/c catalyst. the electrocatalytic performance of the pd/c catalyst for formic acid oxidation in (nh(4))(2)so(4) electrolyte is the best among three electrolytes. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 中文 |
| WOS记录号 | WOS:000293724100028 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44503]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Hong YJ,Shen JZ,Li HZ,et al. Effect of Electrolyte on Electrocatalytic Performance of Carbon Supported Pd Catalyst for Formic Acid Oxidation[J]. chinese journal of inorganic chemistry,2011,27(7):1383-1387. |
| APA | Hong YJ,Shen JZ,Li HZ,Tang YW,&Lu TH.(2011).Effect of Electrolyte on Electrocatalytic Performance of Carbon Supported Pd Catalyst for Formic Acid Oxidation.chinese journal of inorganic chemistry,27(7),1383-1387. |
| MLA | Hong YJ,et al."Effect of Electrolyte on Electrocatalytic Performance of Carbon Supported Pd Catalyst for Formic Acid Oxidation".chinese journal of inorganic chemistry 27.7(2011):1383-1387. |
入库方式： OAI收割
来源：长春应用化学研究所
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