Tunable Luminescence and Energy Transfer properties of Sr(3)AlO(4)F: RE(3+) (RE = Tm/Tb, Eu, Ce) Phosphors
文献类型：期刊论文
| 作者 | Shang MM ; Li GG ; Kang XJ ; Yang DM ; Geng DL ; Lin J |
| 刊名 | acs applied materials & interfaces
 |
| 出版日期 | 2011 |
| 卷号 | 3期号:7页码:2738-2746 |
| 关键词 | LOW-VOLTAGE CATHODOLUMINESCENCE LIGHT-EMITTING DIODES RARE-EARTH IONS OPTICAL-PROPERTIES TB3+ PHOTOLUMINESCENCE EMISSION LEDS OXYFLUORIDES ILLUMINATION |
| ISSN号 | 1944-8244 |
| 通讯作者 | lin j |
| 中文摘要 | sr(3)alo(4)f:re(3+) (re = tm/tb, eu, cc) phosphors were prepared by the conventional solid-state reaction. x-ray diffraction (xrd), field-emission scanning electron microscopy (fe-sem), photoluminescence (pl) spectra, as well as lifetimes were utilized to characterize samples. under the excitation of uv light, sr(3)alo(4)f:tm(3+), sr(3)alo(4)f:tb(3+), and sr(3)alo(4)f:eu(3+) exhibit the characteristic emissions of tm(3+) ((1)d(2)->(3)f(4), blue), tb(3+) ((5)d(4)->(7)e(5), green), and eu(3+) ((5)d(0)->(7)f(2), red), respectively. by adjusting the doping concentration of eu(3+) ions in sr(3)alo(4)f:0.10tm(3+), 0.10tb(3+), zeu(3+), a white emission in a single composition was obtained under the excitation of 360 nm, in which an energy transfer from tb(3+) to eu(3+) was observed. for sr(3)alo(4)f:ce(3+),tb(3+) samples, the energy transfer from ce(3+) to tb(3+) is efficient and demonstrated to be a resonant type via a dipole-quadrupole interaction by comparing the experimental data and theoretical calculation. furthermore, the critical distance of the ce(3+) and tb(3+) ions has also been calculated to be 9.05 angstrom. the corresponding luminescence and energy transfer mechanisms have been proposed in detail. these phosphors might be promising for use in near-uv leds. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44508]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Shang MM,Li GG,Kang XJ,et al. Tunable Luminescence and Energy Transfer properties of Sr(3)AlO(4)F: RE(3+) (RE = Tm/Tb, Eu, Ce) Phosphors[J]. acs applied materials & interfaces,2011,3(7):2738-2746. |
| APA | Shang MM,Li GG,Kang XJ,Yang DM,Geng DL,&Lin J.(2011).Tunable Luminescence and Energy Transfer properties of Sr(3)AlO(4)F: RE(3+) (RE = Tm/Tb, Eu, Ce) Phosphors.acs applied materials & interfaces,3(7),2738-2746. |
| MLA | Shang MM,et al."Tunable Luminescence and Energy Transfer properties of Sr(3)AlO(4)F: RE(3+) (RE = Tm/Tb, Eu, Ce) Phosphors".acs applied materials & interfaces 3.7(2011):2738-2746. |
入库方式： OAI收割
来源：长春应用化学研究所
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