Macrocyclic organotin(IV) carboxylates based on benzenedicarboxylic acid derivatives: Syntheses, crystal structures and antitumor activities
文献类型：期刊论文
| 作者 | Du DF ; Jiang ZJ ; Liu CL ; Sakho AM ; Zhu DS ; Xu L |
| 刊名 | journal of organometallic chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 696期号:13页码:2549-2558 |
| 关键词 | SOLID-STATE STRUCTURES MOLECULAR-STRUCTURE DIMERIC TETRAORGANODISTANNOXANE DIORGANOTIN DERIVATIVES COMPLEXES TIN TRINUCLEAR CLUSTER COORDINATION ASSEMBLIES |
| ISSN号 | 0022-328x |
| 通讯作者 | zhu ds |
| 中文摘要 | six new organotin carboxylates based on 1,3-benzenedicarboxylic acid and 1,4-benzenedicarboxylic acid derivatives, namely (ph(3)sn)(2)(2,5-l(1))(c(2)h(5)oh)(2) (1) (2,5-h(2)l(1) = 2,5-dibenzoylterephthalic acid), (ph(3)sn)(2)(2,5-l(2))(c(2)h(5)oh)(2) (2) (2,5-h(2)l(2) = 2,5-bis(4-methylbenzoyl)terephthalic acid), (ph(3)sn)(2)(2,5-l(3))(c(2)h(5)oh)(2) (3) (2,5-h(2)l(3) = 2,5-bis(4-ethylbenzoyl)terephthalic acid), [(n-bu(2)sn)(4)(4,6-l(1))o(2)(oh)(oc(2)h(5))](2)center dot 2(c(2)h(5)oh) (4) (4,6- h(2)l(1) = 4,6-dibenzoylisophthalic acid), [(n-bu(2)sn)(4)(4,6-l(1))o(2)(oh)(oc(4)h(9))](2)center dot 2(c(4)h(9)oh) (5) and [(n-bu(2)sn)(4)(4,6-l(2))o(2)(oh)(oc(2)h(5))](2)center dot 2(c(2)h(5)oh) (6) (4,6-h(2)l(2) = 4,6-bis(4-methylbenzoyl)isophthalic acid), have been synthesized. all the organotin carboxylates have been characterized by elemental analysis, ir, (1)h and (13)c nmr spectroscopy and x-ray crystallography diffraction analyses. the structural analysis reveals that complexes 1-3 show similar structures, containing binuclear triorganotin skeletons. the significant intermolecular o-h center dot center dot center dot o hydrogen bonds linked the complexes 1-3 to form a novel 2d network polymer with 38-member macrocycles. in complexes 4-6, two sn(4)o(4) ladders are connected by two 1,3-benzenedicarboxylic acid derivatives to yield ladder-like octanuclear architectures and form macrocycle with 24 atoms. in addition, the antitumor activities of complexes 1-6 have been studied. (c) 2011 elsevier b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000291017700013 |
| 公开日期 | 2012-06-08 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44534]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Du DF,Jiang ZJ,Liu CL,et al. Macrocyclic organotin(IV) carboxylates based on benzenedicarboxylic acid derivatives: Syntheses, crystal structures and antitumor activities[J]. journal of organometallic chemistry,2011,696(13):2549-2558. |
| APA | Du DF,Jiang ZJ,Liu CL,Sakho AM,Zhu DS,&Xu L.(2011).Macrocyclic organotin(IV) carboxylates based on benzenedicarboxylic acid derivatives: Syntheses, crystal structures and antitumor activities.journal of organometallic chemistry,696(13),2549-2558. |
| MLA | Du DF,et al."Macrocyclic organotin(IV) carboxylates based on benzenedicarboxylic acid derivatives: Syntheses, crystal structures and antitumor activities".journal of organometallic chemistry 696.13(2011):2549-2558. |
入库方式： OAI收割
来源：长春应用化学研究所
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