Spectroscopic study on water diffusion in aromatic polyamide thin film
文献类型：期刊论文
| 作者 | Jin Y ; Wang W ; Su ZH |
| 刊名 | journal of membrane science
 |
| 出版日期 | 2011 |
| 卷号 | 379期号:1-2页码:121-130 |
| 关键词 | INFRARED CORRELATION SPECTROSCOPY ATR-FTIR EPOXY-RESINS REFLECTION SPECTROSCOPY COMPOSITE MEMBRANES M-PHENYLENEDIAMINE IR SPECTROSCOPY NYLON 12 TRANSPORT COPOLYMERS |
| ISSN号 | 0376-7388 |
| 通讯作者 | su zh |
| 中文摘要 | a clear understanding of water diffusion mechanism is crucial for the design of efficient thin film composite (tfc) membranes for reverse osmosis. in this work, water absorption and desorption processes in poly(metaphenylene trimesamide) (mpta). the active layer of tfc membranes, have been investigated by ftir three different states of water molecules in the film were identified. the spectral data were assessed using 2d correlation analysis, and the sequence of the interactions in the absorption and desorption processes between water and the polymer matrix was determined. the moderately strong bound water hydrogen bonded with -c=o and -nh- occurs first. then water diffuses into free volume (microvoids), exhibiting weak hydrogen bonding interactions, as well as forms strong hydrogen bonds between the polyamide and water molecules. the process of water desorption is just the opposite in terms of the interaction sequence. furthermore, it was found that a higher carboxyl content in the mpta film results in a higher water flux. (c) 2011 elsevier bm. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000294076700012 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44546]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Jin Y,Wang W,Su ZH. Spectroscopic study on water diffusion in aromatic polyamide thin film[J]. journal of membrane science,2011,379(1-2):121-130. |
| APA | Jin Y,Wang W,&Su ZH.(2011).Spectroscopic study on water diffusion in aromatic polyamide thin film.journal of membrane science,379(1-2),121-130. |
| MLA | Jin Y,et al."Spectroscopic study on water diffusion in aromatic polyamide thin film".journal of membrane science 379.1-2(2011):121-130. |
入库方式： OAI收割
来源：长春应用化学研究所
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