中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Protein-Promoted Synthesis of Pt Nanoparticles on Carbon Nanotubes for Electrocatalytic Nanohybrids with Enhanced Glucose Sensing

文献类型:期刊论文

作者Wei G ; Xu FG ; Li Z ; Jandt KD
刊名journal of physical chemistry c
出版日期2011
卷号115期号:23页码:11453-11460
ISSN号1932-7447
关键词NONCOVALENT FUNCTIONALIZATION GOLD NANOPARTICLES PHASE-TRANSFER SINGLE BIOSENSORS COMPOSITES SENSOR WATER SOLUBILIZATION ELECTRODE
通讯作者jandt kd
中文摘要a facile and effective strategy to create carbon nanotube (cnt)-based platinum nanoparticle (ptnp) nanohybrids is reported in this work. first, we prepared toluene-soluble cnts by modifying cnts with a bifunctional linker, z-glycine n-succinimidyl ester (z-gly-osu), and then we synthesized super-water-soluble cnt-hemoglobin (hgb) hybrid nanofibers (about 5 mg/ml) by phase-transferring the z-gly-osu-modified cnts from toluene to hgb aqueous solution. the prepared cnt-hgb nanofibers were used as templates to bind ptcl(6)(2-) ions by electrostatic interaction between proteins and negatively charged ions. cnt-ptnp nanohybrids were successfully synthesized by chemically reducing the ptcl(6)(2-) ions with nabh(4). the results indicate that ptnps with uniform size and shape were created on the side wall of cnts with high dispersion, and the loading of ptnps on cnts was improved with the increase of protein concentration used for the preparation of cnt-hgb nanofibers. a nonenzymatic amperometric sensor for highly sensitive and selective detection of glucose was successfully fabricated as demonstrating based on the synthesized cnt-ptnp nanohybrids. under optimal conditions, selective detection of glucose in a linear concentration range of 28.0 mu m-46.6 mm (r = 0.996) was obtained, which reveals a lower limit of detection and wider linear response compared to some previously reported glucose sensors.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000291339000018
公开日期2012-06-11
源URL[http://ir.ciac.jl.cn/handle/322003/44559]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Wei G,Xu FG,Li Z,et al. Protein-Promoted Synthesis of Pt Nanoparticles on Carbon Nanotubes for Electrocatalytic Nanohybrids with Enhanced Glucose Sensing[J]. journal of physical chemistry c,2011,115(23):11453-11460.
APA Wei G,Xu FG,Li Z,&Jandt KD.(2011).Protein-Promoted Synthesis of Pt Nanoparticles on Carbon Nanotubes for Electrocatalytic Nanohybrids with Enhanced Glucose Sensing.journal of physical chemistry c,115(23),11453-11460.
MLA Wei G,et al."Protein-Promoted Synthesis of Pt Nanoparticles on Carbon Nanotubes for Electrocatalytic Nanohybrids with Enhanced Glucose Sensing".journal of physical chemistry c 115.23(2011):11453-11460.

入库方式: OAI收割

来源:长春应用化学研究所

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