Ru(bpy)(3)(2+) electrochemiluminescence in the presence of formaldehyde or formic acid
文献类型：期刊论文
| 作者 | Hu LZ ; Li HJ ; Han S ; Xu GB |
| 刊名 | journal of electroanalytical chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 656期号:1-2页码:289-292 |
| 关键词 | ELECTROGENERATED CHEMILUMINESCENCE TRIS(2 ELECTRODES 2'-BIPYRIDINE)RUTHENIUM(II) SYSTEM OXIDATION HYDROXYL RADICALS ECL LUMINESCENCE RUTHENIUM |
| ISSN号 | 1572-6657 |
| 通讯作者 | xu gb |
| 中文摘要 | two new electrochemiluminescence (ecl) systems, the ru(bpy)(3)(2+)/formaldehyde system and the ru(bpy)(3)(2+)/formic acid system, have been reported. intense ecl was observed from ru(bpy)(3)(2+) in the presence of formaldehyde or formic acid at glassy carbon electrodes, but not at platinum and gold electrodes. the ecl reactions may involve the oxidation of formaldehyde and formic acid by electrogenerated oh. to form the strong reducing intermediates (center dot)cho and co(2)(-center dot) that react with ru(bpy)(3)(3+) to emit light. the ecl intensity increases linearly with the formaldehyde or formic acid concentration over the range of concentration of 3 mu m-1 mm. the detection limit is 1 mu m for formaldehyde and formic acid. (c) 2010 elsevier b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000291768300047 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44567]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Hu LZ,Li HJ,Han S,et al. Ru(bpy)(3)(2+) electrochemiluminescence in the presence of formaldehyde or formic acid[J]. journal of electroanalytical chemistry,2011,656(1-2):289-292. |
| APA | Hu LZ,Li HJ,Han S,&Xu GB.(2011).Ru(bpy)(3)(2+) electrochemiluminescence in the presence of formaldehyde or formic acid.journal of electroanalytical chemistry,656(1-2),289-292. |
| MLA | Hu LZ,et al."Ru(bpy)(3)(2+) electrochemiluminescence in the presence of formaldehyde or formic acid".journal of electroanalytical chemistry 656.1-2(2011):289-292. |
入库方式： OAI收割
来源：长春应用化学研究所
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