Reaction of hydrous inorganic metal salts in CO(2) expanded ethanol: Fabrication of nanostructured materials via supercritical technology
文献类型：期刊论文
| 作者 | Ming J ; Wu CY ; Cheng HY ; Yu YC ; Zhao FY |
| 刊名 | journal of supercritical fluids
 |
| 出版日期 | 2011 |
| 卷号 | 57期号:2页码:137-142 |
| 关键词 | CARBON-DIOXIDE INFRARED-SPECTRA FLUID ROUTE ASSISTED DEPOSITION FILMS NANOTUBES COPPER NANOCOMPOSITES NANOPARTICLES COMPOSITES |
| ISSN号 | 0896-8446 |
| 通讯作者 | zhao fy |
| 中文摘要 | the fabrication of nanostructured materials from hydrous inorganic metal salt processed in supercritical co(2) (scco(2)) expanded liquids has advantages to obtain good results. however, the behavior of the inorganic salts and the detailed reaction mechanism are still unknown up to now. in this work, the actual behavior of hydrous inorganic metal salts in co(2) expanded ethanol at the temperature of 50-200 degrees c, including the phase behavior, deposition mechanism, reaction rate and the effect of templates on the deposition were systematically investigated by using xrd, ftir, chn-analysis, tga, icp-aes. a series of experimental parameters such as co(2) flow rate, expand procedure, reaction temperature and time have been discussed, as well as the roles of co(2) and h(2)o (often originated from salts and/or solvent but always neglected) were studied in this contribution. significantly, a coordination-decomposition (c-d) was proved to be the converting mechanism for the precipitation of the hydrous inorganic metal salts, rather than the fuzzy decomposition. (c) 2011 elsevier b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44602]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ming J,Wu CY,Cheng HY,et al. Reaction of hydrous inorganic metal salts in CO(2) expanded ethanol: Fabrication of nanostructured materials via supercritical technology[J]. journal of supercritical fluids,2011,57(2):137-142. |
| APA | Ming J,Wu CY,Cheng HY,Yu YC,&Zhao FY.(2011).Reaction of hydrous inorganic metal salts in CO(2) expanded ethanol: Fabrication of nanostructured materials via supercritical technology.journal of supercritical fluids,57(2),137-142. |
| MLA | Ming J,et al."Reaction of hydrous inorganic metal salts in CO(2) expanded ethanol: Fabrication of nanostructured materials via supercritical technology".journal of supercritical fluids 57.2(2011):137-142. |
入库方式： OAI收割
来源：长春应用化学研究所
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