Electrochemiluminescence Determination of Thioridazine Based on Carbon Nanofiber Paste Electrode
文献类型:期刊论文
作者 | Xu L ; Liu Y ; Hou HQ ; You TY |
刊名 | chinese journal of analytical chemistry
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出版日期 | 2011 |
卷号 | 39期号:5页码:635-639 |
关键词 | ELECTROGENERATED CHEMILUMINESCENCE CAPILLARY-ELECTROPHORESIS HUMAN PLASMA ELECTROCHEMISTRY HYDROCHLORIDE SEPARATION ECL |
ISSN号 | 0253-3820 |
通讯作者 | you ty |
中文摘要 | a carbon nanofiber paste electrode (cfpe) was employed for fabrication of electrochemilumunescence (ecl) sensor. the performance of cfpe was characterized by cyclic voltammetry. the electrochemical and ecl behaviors of ru(bpy)(3)(2+) and thioridazine (tr) were investigated. the electrode showed an excellent electrochemical activity and ecl response. based on the fact that the light emission of the ecl sensor could be enhanced by tr dramatically, a new method has been established for the determination of tr. the effects of ph value and concentration of buffer, ru(bpy)(3)(2+) were studied respectively. under the optimum experimental conditions, the ecl sensor exhibited excellent linear response to tr ranging from 2 to 40 mu mol/l (r=0. 998) and a low detection limit of 0. 5 mu mol/l (s/n=3). the relative standard deviation was 1.1% for 15 mu mol/l tr (n=11). the established method was successfully applied for the determination of tr in urine sample with satisfactory results, and the recovery was between 98. 7% and 105. 4%. |
收录类别 | SCI收录期刊论文 |
语种 | 中文 |
WOS记录号 | WOS:000293202300006 |
公开日期 | 2012-06-11 |
源URL | [http://ir.ciac.jl.cn/handle/322003/44655] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Xu L,Liu Y,Hou HQ,et al. Electrochemiluminescence Determination of Thioridazine Based on Carbon Nanofiber Paste Electrode[J]. chinese journal of analytical chemistry,2011,39(5):635-639. |
APA | Xu L,Liu Y,Hou HQ,&You TY.(2011).Electrochemiluminescence Determination of Thioridazine Based on Carbon Nanofiber Paste Electrode.chinese journal of analytical chemistry,39(5),635-639. |
MLA | Xu L,et al."Electrochemiluminescence Determination of Thioridazine Based on Carbon Nanofiber Paste Electrode".chinese journal of analytical chemistry 39.5(2011):635-639. |
入库方式: OAI收割
来源:长春应用化学研究所
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