中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electrochemiluminescence Determination of Thioridazine Based on Carbon Nanofiber Paste Electrode

文献类型:期刊论文

作者Xu L ; Liu Y ; Hou HQ ; You TY
刊名chinese journal of analytical chemistry
出版日期2011
卷号39期号:5页码:635-639
关键词ELECTROGENERATED CHEMILUMINESCENCE CAPILLARY-ELECTROPHORESIS HUMAN PLASMA ELECTROCHEMISTRY HYDROCHLORIDE SEPARATION ECL
ISSN号0253-3820
通讯作者you ty
中文摘要a carbon nanofiber paste electrode (cfpe) was employed for fabrication of electrochemilumunescence (ecl) sensor. the performance of cfpe was characterized by cyclic voltammetry. the electrochemical and ecl behaviors of ru(bpy)(3)(2+) and thioridazine (tr) were investigated. the electrode showed an excellent electrochemical activity and ecl response. based on the fact that the light emission of the ecl sensor could be enhanced by tr dramatically, a new method has been established for the determination of tr. the effects of ph value and concentration of buffer, ru(bpy)(3)(2+) were studied respectively. under the optimum experimental conditions, the ecl sensor exhibited excellent linear response to tr ranging from 2 to 40 mu mol/l (r=0. 998) and a low detection limit of 0. 5 mu mol/l (s/n=3). the relative standard deviation was 1.1% for 15 mu mol/l tr (n=11). the established method was successfully applied for the determination of tr in urine sample with satisfactory results, and the recovery was between 98. 7% and 105. 4%.
收录类别SCI收录期刊论文
语种中文
WOS记录号WOS:000293202300006
公开日期2012-06-11
源URL[http://ir.ciac.jl.cn/handle/322003/44655]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Xu L,Liu Y,Hou HQ,et al. Electrochemiluminescence Determination of Thioridazine Based on Carbon Nanofiber Paste Electrode[J]. chinese journal of analytical chemistry,2011,39(5):635-639.
APA Xu L,Liu Y,Hou HQ,&You TY.(2011).Electrochemiluminescence Determination of Thioridazine Based on Carbon Nanofiber Paste Electrode.chinese journal of analytical chemistry,39(5),635-639.
MLA Xu L,et al."Electrochemiluminescence Determination of Thioridazine Based on Carbon Nanofiber Paste Electrode".chinese journal of analytical chemistry 39.5(2011):635-639.

入库方式: OAI收割

来源:长春应用化学研究所

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