中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Preparation of PVDF-based polymer inclusion membrane using ionic liquid plasticizer and Cyphos IL 104 carrier for Cr(VI) transport

文献类型:期刊论文

作者Guo L ; Liu YH ; Zhang C ; Chen J
刊名journal of membrane science
出版日期2011
卷号372期号:1-2页码:314-321
关键词ANION-EXCHANGE MEMBRANES TRI-N-OCTYLAMINE AQUEOUS-SOLUTIONS FACILITATED TRANSPORT CHROMIUM(VI) TRANSPORT PHOSPHINE OXIDES SILICA MATERIALS RARE-EARTHS EXTRACTION REMOVAL
ISSN号0376-7388
通讯作者chen j
中文摘要a new type of polymer inclusion membrane (pim) was prepared and applied in cr(vi) transport. the novel pims are composed of three main components: poly(vinylidene fluoride) (pvdf) as support, 1-alkyl-3-methylimidazolium hexafluorophosphate or tetrafluoroborate ([c(n)mim][pf(6)] or [bf(4)] (n = 4,8)) as ionic liquid plasticizers (ilps) and phosphonium il trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate (cyphos il 104) as carrier. the effective contact area of membrane for cr(vi) transport was increased due to the enhanced surface roughness and the contact angle by using ilps, which also led to the permeability coefficient (p) increasing four times faster than that without ilps. it was found that [c(8)mim][bf(4)] as plasticizer had the maximum p value 19.64 mu m s(-1). the flux of cr(vi) was affected by both hcl concentration in feed phase and naoh concentration in stripping phase. the p of membrane with cyphos il 104 as carrier was 13 times faster than that of aliquat 336. compared with supported liquid membrane (slm) and other pims, longer reusability and larger flux were found for the new prepared pims. (c) 2011 elsevier b.v. all rights reserved.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000289829200034
公开日期2012-06-11
源URL[http://ir.ciac.jl.cn/handle/322003/44700]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Guo L,Liu YH,Zhang C,et al. Preparation of PVDF-based polymer inclusion membrane using ionic liquid plasticizer and Cyphos IL 104 carrier for Cr(VI) transport[J]. journal of membrane science,2011,372(1-2):314-321.
APA Guo L,Liu YH,Zhang C,&Chen J.(2011).Preparation of PVDF-based polymer inclusion membrane using ionic liquid plasticizer and Cyphos IL 104 carrier for Cr(VI) transport.journal of membrane science,372(1-2),314-321.
MLA Guo L,et al."Preparation of PVDF-based polymer inclusion membrane using ionic liquid plasticizer and Cyphos IL 104 carrier for Cr(VI) transport".journal of membrane science 372.1-2(2011):314-321.

入库方式: OAI收割

来源:长春应用化学研究所

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