Preparation of PVDF-based polymer inclusion membrane using ionic liquid plasticizer and Cyphos IL 104 carrier for Cr(VI) transport
文献类型:期刊论文
作者 | Guo L ; Liu YH ; Zhang C ; Chen J |
刊名 | journal of membrane science
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出版日期 | 2011 |
卷号 | 372期号:1-2页码:314-321 |
关键词 | ANION-EXCHANGE MEMBRANES TRI-N-OCTYLAMINE AQUEOUS-SOLUTIONS FACILITATED TRANSPORT CHROMIUM(VI) TRANSPORT PHOSPHINE OXIDES SILICA MATERIALS RARE-EARTHS EXTRACTION REMOVAL |
ISSN号 | 0376-7388 |
通讯作者 | chen j |
中文摘要 | a new type of polymer inclusion membrane (pim) was prepared and applied in cr(vi) transport. the novel pims are composed of three main components: poly(vinylidene fluoride) (pvdf) as support, 1-alkyl-3-methylimidazolium hexafluorophosphate or tetrafluoroborate ([c(n)mim][pf(6)] or [bf(4)] (n = 4,8)) as ionic liquid plasticizers (ilps) and phosphonium il trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate (cyphos il 104) as carrier. the effective contact area of membrane for cr(vi) transport was increased due to the enhanced surface roughness and the contact angle by using ilps, which also led to the permeability coefficient (p) increasing four times faster than that without ilps. it was found that [c(8)mim][bf(4)] as plasticizer had the maximum p value 19.64 mu m s(-1). the flux of cr(vi) was affected by both hcl concentration in feed phase and naoh concentration in stripping phase. the p of membrane with cyphos il 104 as carrier was 13 times faster than that of aliquat 336. compared with supported liquid membrane (slm) and other pims, longer reusability and larger flux were found for the new prepared pims. (c) 2011 elsevier b.v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000289829200034 |
公开日期 | 2012-06-11 |
源URL | [http://ir.ciac.jl.cn/handle/322003/44700] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Guo L,Liu YH,Zhang C,et al. Preparation of PVDF-based polymer inclusion membrane using ionic liquid plasticizer and Cyphos IL 104 carrier for Cr(VI) transport[J]. journal of membrane science,2011,372(1-2):314-321. |
APA | Guo L,Liu YH,Zhang C,&Chen J.(2011).Preparation of PVDF-based polymer inclusion membrane using ionic liquid plasticizer and Cyphos IL 104 carrier for Cr(VI) transport.journal of membrane science,372(1-2),314-321. |
MLA | Guo L,et al."Preparation of PVDF-based polymer inclusion membrane using ionic liquid plasticizer and Cyphos IL 104 carrier for Cr(VI) transport".journal of membrane science 372.1-2(2011):314-321. |
入库方式: OAI收割
来源:长春应用化学研究所
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