Synthesis of amphiphilic poly(cyclooctene)-graft-poly(ethylene glycol) copolymers via ROMP and its surface properties
文献类型：期刊论文
| 作者 | Shi HC ; Shi DA ; Yao ZH ; Luan SF ; Jin J ; Zhao J ; Yang HW ; Stagnaro P ; Yin JH |
| 刊名 | polymer chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 2期号:3页码:679-684 |
| 关键词 | OPENING METATHESIS POLYMERIZATION TRANSFER RADICAL POLYMERIZATION POLY(ETHYLENE GLYCOL) PROTEIN RESISTANCE POLYMERS ADSORPTION ADHESION CATALYST BRUSHES CLICK |
| ISSN号 | 1759-9954 |
| 通讯作者 | shi da |
| 中文摘要 | macromonomer cyclooctene-poly(ethylene glycol) (cyclooctene-peg) was first synthesized before being copolymerized with cyclooctene by ring opening metathesis polymerization (romp) to obtain an amphiphilic graft copolymer (poly(cyclooctene)-g-peg) with polycyclooctene as the hydrophobic trunk chain and peg as hydrophilic side chains. the structure of poly(cyclooctene)-g-peg copolymer was characterized by ftir and (1)h-nmr. the surface properties of poly(cyclooctene)-g-peg film were evaluated through water contact angle and x-ray photoelectron spectroscopy (xps). water contact angle decreased from 87.7 degrees to 65.8 degrees along with increasing the content of peg. protein adsorption results showed that poly(cyclooctene)-g-peg copolymers had significant effect on preventing bovine serum albumin (bsa) from absorbing onto the polymer surface. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000287378000030 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44792]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Shi HC,Shi DA,Yao ZH,et al. Synthesis of amphiphilic poly(cyclooctene)-graft-poly(ethylene glycol) copolymers via ROMP and its surface properties[J]. polymer chemistry,2011,2(3):679-684. |
| APA | Shi HC.,Shi DA.,Yao ZH.,Luan SF.,Jin J.,...&Yin JH.(2011).Synthesis of amphiphilic poly(cyclooctene)-graft-poly(ethylene glycol) copolymers via ROMP and its surface properties.polymer chemistry,2(3),679-684. |
| MLA | Shi HC,et al."Synthesis of amphiphilic poly(cyclooctene)-graft-poly(ethylene glycol) copolymers via ROMP and its surface properties".polymer chemistry 2.3(2011):679-684. |
入库方式： OAI收割
来源：长春应用化学研究所
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