Highly Efficient Suzuki-Miyaura Coupling of Aryl Tosylates and Mesylates Catalyzed by Stable, Cost-Effective [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride [Ni(dppp)Cl(2)] with only 1 mol% Loading
文献类型：期刊论文
| 作者 | Gao H ; Li Y ; Zhou YG ; Han FS ; Lin YJ |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2011 |
| 卷号 | 353期号:2-3页码:309-314 |
| 关键词 | ARYLBORONIC ACIDS BORONIC ACIDS C-N PALLADIUM ARENESULFONATES AMINATION NICKEL HALIDES SYSTEM BISTERPYRIDINES |
| ISSN号 | 1615-4150 |
| 通讯作者 | han fs |
| 中文摘要 | we present a highly active, inexpensive, universally applicable, and markedly stable [1,3-bis(diphenylphosphino)propane]nickel(ii) chloride [ni(dppp)cl(2)] catalyst that is capable of effecting the suzuki-miyaura cross-coupling of the inherently less reactive but readily available aryl tosylates and mesylates with only 1 mol% loading and in the absence of extra supporting ligand. under the optimized reaction conditions, cross-coupling of a wide range of activated, non-activated, and deactivated, as well as sterically hindered and heteroaromatic substrates (36 examples) could proceed efficiently to afford the coupled products in 53-99% yields. consequently, the results presented in this work provide a significant advance in suzuki-miyaura cross-coupling in terms of generality, practicality, and cost which are key concerns in recent research regarding transition metal-catalyzed cross-couplings. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44823]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gao H,Li Y,Zhou YG,et al. Highly Efficient Suzuki-Miyaura Coupling of Aryl Tosylates and Mesylates Catalyzed by Stable, Cost-Effective [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride [Ni(dppp)Cl(2)] with only 1 mol% Loading[J]. advanced synthesis & catalysis,2011,353(2-3):309-314. |
| APA | Gao H,Li Y,Zhou YG,Han FS,&Lin YJ.(2011).Highly Efficient Suzuki-Miyaura Coupling of Aryl Tosylates and Mesylates Catalyzed by Stable, Cost-Effective [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride [Ni(dppp)Cl(2)] with only 1 mol% Loading.advanced synthesis & catalysis,353(2-3),309-314. |
| MLA | Gao H,et al."Highly Efficient Suzuki-Miyaura Coupling of Aryl Tosylates and Mesylates Catalyzed by Stable, Cost-Effective [1,3-Bis(diphenylphosphino)propane]nickel(II) Chloride [Ni(dppp)Cl(2)] with only 1 mol% Loading".advanced synthesis & catalysis 353.2-3(2011):309-314. |
入库方式： OAI收割
来源：长春应用化学研究所
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