Star-Shaped Oligotriarylamines with Planarized Triphenylamine Core: Solution-Processable, High-T(g) Hole-Injecting and Hole-Transporting Materials for Organic Light-Emitting Devices
文献类型：期刊论文
| 作者 | Jiang ZQ ; Ye TL ; Yang CL ; Yang DZ ; Zhu MR ; Zhong C ; Qin JG ; Ma DG |
| 刊名 | chemistry of materials
 |
| 出版日期 | 2011 |
| 卷号 | 23期号:3页码:771-777 |
| 关键词 | AMORPHOUS MOLECULAR MATERIALS METHYL-SUBSTITUTED DERIVATIVES PHOSPHORESCENT OLEDS CONJUGATED POLYMERS DIODES TRIARYLAMINES ELECTROLUMINESCENCE PERFORMANCE DENDRIMERS STABILITY |
| ISSN号 | 0897-4756 |
| 通讯作者 | yang cl |
| 中文摘要 | two novel star-shaped oligotriarylamines with planar triphenylamine core and peripheral triarylamine groups, namely fatpa-t and fatpa-cz, were synthesized by suzuki cross-coupling reaction. the molecular design imparts the materials with the following features: (i) excellent thermal stabilities with quite high glass transition temperatures (237 degrees c for fatpa-t and 272 degrees c for fatpa-cz); (ii) good solution-processability; (iii) good hole mobility, efficient hole injection, and electron-blocking functions. furthermore, their optoelectronic properties can be modulated by the peripheral triarylamine groups. for example, fatpa-t with triphenylamine peripheries shows the significantly red-shifted absorption and emission, as well as the small band gap as compared to fatpa-cz with carbazole peripheries. double-layer alq(3)-emitting oleds using fatpa-t or fatpa-cz as hole-transport layer by spin-coating method were fabricated, and the fatpa-cz-based devices show greatly improved performance as compared to standard npb-based device by vacuum-evaporation of npb. the optimized three-layer alq(3)-emitting oleds by using fatpa-cz and npb as double hole-transport layers exhibit the maximum current efficiency of 6.83 cd/a, which is the highest for the alq3-based green emission under the similar device structures. the advantages of solution-processablity and very high t(g) make the star-shaped oligotriarylamines ideal substitutes for conventional arylamines as hole-inject and hole-transport materials. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44832]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Jiang ZQ,Ye TL,Yang CL,et al. Star-Shaped Oligotriarylamines with Planarized Triphenylamine Core: Solution-Processable, High-T(g) Hole-Injecting and Hole-Transporting Materials for Organic Light-Emitting Devices[J]. chemistry of materials,2011,23(3):771-777. |
| APA | Jiang ZQ.,Ye TL.,Yang CL.,Yang DZ.,Zhu MR.,...&Ma DG.(2011).Star-Shaped Oligotriarylamines with Planarized Triphenylamine Core: Solution-Processable, High-T(g) Hole-Injecting and Hole-Transporting Materials for Organic Light-Emitting Devices.chemistry of materials,23(3),771-777. |
| MLA | Jiang ZQ,et al."Star-Shaped Oligotriarylamines with Planarized Triphenylamine Core: Solution-Processable, High-T(g) Hole-Injecting and Hole-Transporting Materials for Organic Light-Emitting Devices".chemistry of materials 23.3(2011):771-777. |
入库方式： OAI收割
来源：长春应用化学研究所
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