Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex
文献类型:期刊论文
作者 | Ning ZL ; Ding JY ; Jin RZ ; Kang CQ ; Cheng YQ ; Gao LX |
刊名 | chemical research in chinese universities
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出版日期 | 2011 |
卷号 | 27期号:1页码:45-48 |
关键词 | HALOCYCLIZATION IODOCYCLIZATION EPOXIDATION |
ISSN号 | 1005-9040 |
通讯作者 | gao lx |
中文摘要 | a number of salen-metal complexes were prepared and their enantioselective catalytic properties toward the asymmetric iodolactonization of (e)- and (z)-5-substituted-4-pentenoic acid derivatives were investigated. the catalyst system based on salen-co(ii) complex exhibited moderate to good enantioselectivity with the e.e. value ranging from 53% to 74%, as well as high regioselectivity of delta- vs. gamma-iodolactoncs. the salen-co(11) complex showed the highest enantioselectivity on the asymmetric iodolactonizations of (z)-5-substituted-4-pentenoic acid derivatives among these reagent-controlled iodolactonization protocols known so far. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000287825400010 |
公开日期 | 2012-06-11 |
源URL | [http://ir.ciac.jl.cn/handle/322003/44868] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Ning ZL,Ding JY,Jin RZ,et al. Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex[J]. chemical research in chinese universities,2011,27(1):45-48. |
APA | Ning ZL,Ding JY,Jin RZ,Kang CQ,Cheng YQ,&Gao LX.(2011).Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex.chemical research in chinese universities,27(1),45-48. |
MLA | Ning ZL,et al."Enantioselective Iodolactonizations of (E)- and (Z)-5-Substituted-4-pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex".chemical research in chinese universities 27.1(2011):45-48. |
入库方式: OAI收割
来源:长春应用化学研究所
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