New Inorganic-organic Hybrid Tetravanadate: Preparation, Characterization and Application in Chemically Modified Electrode
文献类型：期刊论文
| 作者 | Sun YH ; Li XP ; Mei ZM ; Zhu Y ; Niu L |
| 刊名 | chemical research in chinese universities
 |
| 出版日期 | 2011 |
| 卷号 | 27期号:1页码:6-10 |
| 关键词 | SINGLE-CRYSTAL STRUCTURE LAYERED VANADIUM-OXIDES HYDROTHERMAL SYNTHESIS STRUCTURAL-CHARACTERIZATION MAGNETIC-PROPERTIES COMPLEX POLYOXOMETALATE VANADATES LIQUID CARBON |
| ISSN号 | 1005-9040 |
| 通讯作者 | niu l |
| 中文摘要 | a new inorganic-organic hybrid tetravanadate [co(2,2'-bpy)(3)](7)v(4)o(12)center dot 11h(2)o(1) has been prepared and characterized. x-ray diffraction study reveals that compound 1 contains classical cluster anions [v(4)o(12)](4-), coordinated cations [co(2,2'-bpy)(3)](2+) and eleven water molecules, in which an interesting decamer water cluster is formed. the hybrid nanoparticles were firstly used as a bulk-modifier to fabricate a chemically modified paste electrode (1-cpe). the electrochemical behavior and electrocatalysis of 1-cpe have been studied in detail. the results indicate that 1-cpe has a good electrocatalytic activity toward the reduction of bromatc in a 0.5 mol/l h(2)so(4) aqueous solution. 1-cpe shows remarkable stability that be ascribed to the hydrogen bonding interactions between v(4)o(12) cluster and water cluster, which are very important for practical application in electrode modification. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000287825400002 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44869]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Sun YH,Li XP,Mei ZM,et al. New Inorganic-organic Hybrid Tetravanadate: Preparation, Characterization and Application in Chemically Modified Electrode[J]. chemical research in chinese universities,2011,27(1):6-10. |
| APA | Sun YH,Li XP,Mei ZM,Zhu Y,&Niu L.(2011).New Inorganic-organic Hybrid Tetravanadate: Preparation, Characterization and Application in Chemically Modified Electrode.chemical research in chinese universities,27(1),6-10. |
| MLA | Sun YH,et al."New Inorganic-organic Hybrid Tetravanadate: Preparation, Characterization and Application in Chemically Modified Electrode".chemical research in chinese universities 27.1(2011):6-10. |
入库方式： OAI收割
来源：长春应用化学研究所
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