Highly selective recognition of naphthol isomers based on the fluorescence dye-incorporated SH-beta-cyclodextrin functionalized gold nanoparticles
文献类型：期刊论文
| 作者 | Li XK ; Liu DJ ; Wang ZX |
| 刊名 | biosensors & bioelectronics
 |
| 出版日期 | 2011 |
| 卷号 | 26期号:5页码:2329-2333 |
| 关键词 | MOLECULAR RECOGNITION WATER SAMPLES QUANTUM DOTS BINDING CHROMATOGRAPHY 2-NAPHTHOL 1-NAPHTHOL SURFACTANT COMPLEXES ELECTRODE |
| ISSN号 | 0956-5663 |
| 通讯作者 | wang zx |
| 中文摘要 | in present work, a rhodamine 6g (rh 6g)-incorporated beta-cyclodextrin functionalized gold nanoparticle (rh 6g-cd-aunp) based fluorescent assay has been successfully developed for recognizing/detecting the structural isomers, alpha-naphthol and beta-naphthol, in aqueous solution. the beta-cyclodextrin functionalized gold nanoparticles (cd-aunps) are achieved by conjugating the thiolated beta-cyclodextrin (sh-beta-cd) with aunps via s-au covalent bonds. rhodamine 6g (rh 6g) is chosen as a fluorescent probe in this approach because it can be strongly absorbed on the surface of aunp by noncovalent interaction. after binding with beta-cd cavity, the naphthols enable to act as electron transfer quenchers of rh 6g, which lead to significant fluorescence quenching of the dye. because of different association ability of naphthol isomers with the beta-cd cavity, the assay can selectively distinguish alpha-naphthol and beta-naphthol with reasonable sensitivity. detection of naphthols down to 8 nm with a dynamic range of nearly three orders of magnitude (0.01-8 mu m) for alpha-naphthol and 50 nm with two orders of magnitude (0.1-20 mu m) for beta-naphthol is demonstrated, respectively. the ability of the method for detecting the content of alpha-naphthol or beta-naphthol in the different naphthol mixtures has also been evaluated. (c) 2010 elsevier b.v. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000286904400087 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44889]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li XK,Liu DJ,Wang ZX. Highly selective recognition of naphthol isomers based on the fluorescence dye-incorporated SH-beta-cyclodextrin functionalized gold nanoparticles[J]. biosensors & bioelectronics,2011,26(5):2329-2333. |
| APA | Li XK,Liu DJ,&Wang ZX.(2011).Highly selective recognition of naphthol isomers based on the fluorescence dye-incorporated SH-beta-cyclodextrin functionalized gold nanoparticles.biosensors & bioelectronics,26(5),2329-2333. |
| MLA | Li XK,et al."Highly selective recognition of naphthol isomers based on the fluorescence dye-incorporated SH-beta-cyclodextrin functionalized gold nanoparticles".biosensors & bioelectronics 26.5(2011):2329-2333. |
入库方式： OAI收割
来源：长春应用化学研究所
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