Three three-dimensional anionic metal-organic frameworks with (4,8)-connected alb topology constructed from a semi-rigid ligand and polynuclear metal clusters
文献类型：期刊论文
| 作者 | Su SQ ; Qin C ; Song SY ; Guo ZY ; Deng RP ; Chen W ; Song XZ ; Wang S ; Li GH ; Zhang HJ |
| 刊名 | crystengcomm
 |
| 出版日期 | 2011 |
| 卷号 | 13期号:20页码:6057-6064 |
| 关键词 | METHYLENEDIISOPHTHALIC ACID H4MDIP TRINUCLEAR MANGANESE(II) COMPLEX BUILDING-BLOCKS SBBS COORDINATION POLYMERS FLUORITE TOPOLOGY HIGH-CONNECTIVITY GAS-ADSORPTION NETWORK COBALT(II) SORPTION |
| ISSN号 | 1466-8033 |
| 通讯作者 | zhang hj |
| 中文摘要 | three three-dimensional coordination polymers, namely, [nh(2)(ch(3))(2)][co(2)(mdip)(oh)(h(2)o)]center dot c(3)h(7)no center dot h(2)o (1), [nh(2)(ch(3))(2)](2)[mn(3)(mdip)(2)]center dot 2c(3)h(7)no (2), and [nh(2)(ch(3))(2)][mg(3)(mdip)(hmdip) (c(3)h(7)no)]center dot 4h(2)o (3) (dmf = n,n'-dimethylformamide), have been synthesized by the solvothermal reaction of co(ii), mn(ii), or mg(ii) salts with methylenediisophthalic acid(h(4)mdip). all compounds have been characterized by thermogravimetric analysis, ir spectroscopy, elemental and single-crystal x-ray diffraction analyses. complexes 1-3 are anionic frameworks with [nh(2)(ch(3))(2)](+) ions occupying the voids, built upon tetra-, tri- and asymmetrical trimetallic cores, respectively. in particular, the asymmetrical trinuclear mg(ii) unit in complex 3 was scarcely observed. topological analyses show that the three compounds possess binodal (4,8)-connected alb topology with a schlafli symbol of (4(10).6(14).8(4))(4(5).6)(2). magnetic investigations indicate that antiferromagnetic couplings are dominant in compounds 1 and 2. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000295810300018 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44933]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Su SQ,Qin C,Song SY,et al. Three three-dimensional anionic metal-organic frameworks with (4,8)-connected alb topology constructed from a semi-rigid ligand and polynuclear metal clusters[J]. crystengcomm,2011,13(20):6057-6064. |
| APA | Su SQ.,Qin C.,Song SY.,Guo ZY.,Deng RP.,...&Zhang HJ.(2011).Three three-dimensional anionic metal-organic frameworks with (4,8)-connected alb topology constructed from a semi-rigid ligand and polynuclear metal clusters.crystengcomm,13(20),6057-6064. |
| MLA | Su SQ,et al."Three three-dimensional anionic metal-organic frameworks with (4,8)-connected alb topology constructed from a semi-rigid ligand and polynuclear metal clusters".crystengcomm 13.20(2011):6057-6064. |
入库方式： OAI收割
来源：长春应用化学研究所
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