Kinetics of electron recombination of dye-sensitized solar cells based on TiO(2) nanorod arrays sensitized with different dyes
文献类型:期刊论文
作者 | Wang HX ; Liu MN ; Zhang M ; Wang P ; Miura H ; Cheng Y ; Bell J |
刊名 | physical chemistry chemical physics
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出版日期 | 2011 |
卷号 | 13期号:38页码:17359-17366 |
关键词 | FREE ORGANIC-DYES NANOTUBE-ARRAYS CHARGE-TRANSFER BACK-REACTION TRANSPORT CONVERSION ANATASE RUTILE LIGHT SEMICONDUCTOR |
ISSN号 | 1463-9076 |
通讯作者 | wang hx |
中文摘要 | the performance and electron recombination kinetics of dye-sensitized solar cells based on tio(2) films consisting of one-dimensional nanorod arrays (nr-dsscs) which are sensitized with dyes n719, c218 and d205, respectively, have been studied. it has been found that the best efficiency is obtained with the dye c218 based nr-dsscs, benefiting from a 40% higher short-circuit photocurrent density. however, the open circuit photovoltage of the n719 based cell is 40 mv higher than that of the organic dye c218 and d205 based devices. investigation of the electron recombination kinetics of the nr-dsscs has revealed that the effective electron lifetime, tau(n), of the different dye based nr-dsscs shows the sequence of c218 > d205 > n719. the higher v(oc) with the n719 based nr-dssc is originated from the more negative energy level of the conduction band of the tio(2) film. in addition, in comparison to the dsscs with the conventional nanocrystalline particles based tio(2) films, the nr-dsscs have shown over two orders of magnitude higher tau(n) when employing n719 as the sensitizer. nevertheless, the tau(n) of the dsscs with the c218 based nanorod arrays is only ten-fold higher than that of the nanoparticles based devices. the remarkable characteristic of the dye c218 in suppressing the electron recombination of dsscs is discussed. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2012-06-11 |
源URL | [http://ir.ciac.jl.cn/handle/322003/44943] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Wang HX,Liu MN,Zhang M,et al. Kinetics of electron recombination of dye-sensitized solar cells based on TiO(2) nanorod arrays sensitized with different dyes[J]. physical chemistry chemical physics,2011,13(38):17359-17366. |
APA | Wang HX.,Liu MN.,Zhang M.,Wang P.,Miura H.,...&Bell J.(2011).Kinetics of electron recombination of dye-sensitized solar cells based on TiO(2) nanorod arrays sensitized with different dyes.physical chemistry chemical physics,13(38),17359-17366. |
MLA | Wang HX,et al."Kinetics of electron recombination of dye-sensitized solar cells based on TiO(2) nanorod arrays sensitized with different dyes".physical chemistry chemical physics 13.38(2011):17359-17366. |
入库方式: OAI收割
来源:长春应用化学研究所
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