Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides
文献类型：期刊论文
| 作者 | Huang W ; Li BX ; Wang YH ; Zhang WJ ; Wang L ; Li YS ; Sun WH ; Redshaw C |
| 刊名 | catalysis science & technology
 |
| 出版日期 | 2011 |
| 卷号 | 1期号:7页码:1208-1215 |
| 关键词 | OLEFIN POLYMERIZATION CATALYSTS C-13 NMR-SPECTRA FI CATALYSTS PHENOXYTITANIUM DICHLORIDES TITANIUM(IV) COMPLEXES SEQUENCE DISTRIBUTIONS NORBORNENE COPOLYMERS COCATALYST SYSTEMS BLOCK-COPOLYMERS DONOR LIGANDS |
| ISSN号 | 2044-4753 |
| 通讯作者 | huang w |
| 中文摘要 | the series of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate dichlorides, cp'ticl(2)l (cp' = eta(5)-c(5)h(5) or eta(5)-c(5)me(5), l = 2-(1-(2,6-r(1)-4-r(2)-phenylimino)ethyl)quinolin-8-olate), was synthesized via the stoichiometric reaction of cp'ticl(3) with the corresponding potassium salt, viz. 2-(1-(2,6-r(1)-4-r(2)-phenylimino)ethyl)quinolin-8-olate. all compounds were characterized by elemental analysis, (1)h and (13)c nmr spectroscopy. the molecular structures of complexes c2 and c4 were determined by single-crystal x-ray diffraction. when activated with methylaluminoxane (mao), all half-titanocene pre-catalysts exhibited high activities for ethylene polymerization and co-polymerization with alpha-olefins or norbornene. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000295000900018 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44945]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Huang W,Li BX,Wang YH,et al. Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides[J]. catalysis science & technology,2011,1(7):1208-1215. |
| APA | Huang W.,Li BX.,Wang YH.,Zhang WJ.,Wang L.,...&Redshaw C.(2011).Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides.catalysis science & technology,1(7),1208-1215. |
| MLA | Huang W,et al."Synthesis, characterization and ethylene (co-)polymerization behavior of half-titanocene 2-(1-(arylimino)ethyl)quinolin-8-olate chlorides".catalysis science & technology 1.7(2011):1208-1215. |
入库方式： OAI收割
来源：长春应用化学研究所
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