Monodisperse Gd2O3:Ln (Ln = Eu3+, Tb3+, Dy3+, Sm3+, Yb3+/Er3+, Yb3+/Tm3+, and Yb3+/Ho3+) nanocrystals with tunable size and multicolor luminescent properties
文献类型:期刊论文
作者 | Gai SL ; Yang PP ; Wang D ; Li CX ; Niu N ; He F ; Li XB |
刊名 | crystengcomm
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出版日期 | 2011 |
卷号 | 13期号:17页码:5480-5487 |
关键词 | VISIBLE UP-CONVERSION SPRAY-PYROLYSIS DOPED GD2O3 NANOPARTICLES PARTICLES PHOSPHORS Y2O3-EU MORPHOLOGY NANOTUBES NANORODS |
ISSN号 | 1466-8033 |
通讯作者 | yang pp |
中文摘要 | multicolor and monodisperse gd2o3: ln (ln = eu3+, tb3+, dy3+, sm3+, yb3+/er3+, yb3+/tm3+, and yb3+/ho3+) nanocrystals (ncs) with narrow size distribution were prepared by a homogeneous precipitation method followed by a subsequent calcination process. x-ray diffraction (xrd), scanning electron microscopy (sem), transmission electron microscopy (tem), fourier transformed infrared (ft-ir), thermogravimetric and differential thermal analysis (tg-dta), photoluminescence (pl) spectra, cathodoluminescence (cl) spectra, and kinetic decays were employed to characterize the samples. the results show that the gd2o3: ln ncs can be directly indexed to cubic gd2o3 phase with high purity. and the possible formation mechanism and the chemical reaction of each step to form spherical gd2o3: ln ncs are proposed according to the concerned analysis. upon ultraviolet and low-voltage electron beams excitation, gd2o3:ln (ln = eu3+, tb3+, dy3+, and sm3+) ncs exhibit respective bright red (eu3+, d-5(0) -> f-7(2)), green (tb3+, d-5(4) -> f-gamma(5)), blue (dy3+, f-4(9/2) -> h-6(13/2)) and yellow (sm3+, (4)g(5/2) -> h-6(7/2)) down-conversion (dc) emissions. under 980 nm nir irradiation, gd2o3: ln (ln yb3+/er3+, yb3+/tm3+, and yb3+/ho3+) exhibit characteristic up-conversion (uc) emissions of er3+, tm3+, and ho3+, respectively. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000293693200033 |
公开日期 | 2012-06-11 |
源URL | [http://ir.ciac.jl.cn/handle/322003/44947] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Gai SL,Yang PP,Wang D,et al. Monodisperse Gd2O3:Ln (Ln = Eu3+, Tb3+, Dy3+, Sm3+, Yb3+/Er3+, Yb3+/Tm3+, and Yb3+/Ho3+) nanocrystals with tunable size and multicolor luminescent properties[J]. crystengcomm,2011,13(17):5480-5487. |
APA | Gai SL.,Yang PP.,Wang D.,Li CX.,Niu N.,...&Li XB.(2011).Monodisperse Gd2O3:Ln (Ln = Eu3+, Tb3+, Dy3+, Sm3+, Yb3+/Er3+, Yb3+/Tm3+, and Yb3+/Ho3+) nanocrystals with tunable size and multicolor luminescent properties.crystengcomm,13(17),5480-5487. |
MLA | Gai SL,et al."Monodisperse Gd2O3:Ln (Ln = Eu3+, Tb3+, Dy3+, Sm3+, Yb3+/Er3+, Yb3+/Tm3+, and Yb3+/Ho3+) nanocrystals with tunable size and multicolor luminescent properties".crystengcomm 13.17(2011):5480-5487. |
入库方式: OAI收割
来源:长春应用化学研究所
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