Tunable luminescence of Ce(3+)/Mn(2+)-coactivated Ca(2)Gd(8)(SiO(4))(6)O(2) through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors
文献类型：期刊论文
| 作者 | Li GG ; Geng DL ; Shang MM ; Peng C ; Cheng ZY ; Lin J |
| 刊名 | journal of materials chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 21期号:35页码:13334-13344 |
| 关键词 | FIELD-EMISSION DISPLAYS RARE-EARTH CATHODOLUMINESCENT PROPERTIES NANOCRYSTALLINE PHOSPHORS PROMISING PHOSPHORS SITE OCCUPATION WHITE LEDS IONS TB3+ DIODES |
| ISSN号 | 0959-9428 |
| 通讯作者 | lin j |
| 中文摘要 | ce(3+)/mn(2+)-coactivated ca(2)gd(8)(sio(4))(6)o(2) (cgs) oxyapatite phosphors have been prepared via high temperature solid state reaction process. the ce(3+) emission at different lattice sites has been identified and discussed. the energy transfer from ce(3+) to mn(2+) in cgs : ce(3+)/mn(2+) phosphors has been validated and demonstrated to be a resonant type via a dipole-quadrupole mechanism, and the critical distance (rc) calculated by quenching concentration method and spectral overlap method are 9.4 angstrom and 9.2 angstrom, respectively. a color-tunable emission in cgs : ce(3+)/mn(2+) phosphors can be realized by the modulation of excitation wavelengths, namely, the change of ce(3+) emission at different lattice sites and the relative pl intensity of ce(3+) and mn(2+). in addition, the cathodoluminescence (cl) properties of cgs : ce(3+)/mn(2+) phosphors including the cl spectra, the dependence of cl intensity on accelerating voltage and filament current, the decay behavior of cl intensity under electron bombardment, and the stability of cie chromaticity coordinate have been investigated in detail. the results indicate that the as-prepared cgs : ce(3+)/mn(2+) phosphors have a good cl intensity stability and cie coordinate stability with a color-tunable emission from blue to yellow, crossing the white area by the energy transfer from ce(3+) to m(n2)+ under low-voltage electron beam excitation. in conclusion, the wide-ranged white light with varied hues have been obtained in ce(3+) and mn(2+) coactivated cgs phosphors by utilizing the principle of energy transfer and properly designed activator contents as well as the selection of excitation wavelength under uv (287-352 nm) and low-voltage (1-7 kv) electron beam excitation. therefore, the cgs : ce(3+)/mn(2+) phosphors may potentially be used as single-phased white/yellow-emitting phosphor for uv leds (light emitting diodes) and feds (field emission displays). |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44954]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li GG,Geng DL,Shang MM,et al. Tunable luminescence of Ce(3+)/Mn(2+)-coactivated Ca(2)Gd(8)(SiO(4))(6)O(2) through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors[J]. journal of materials chemistry,2011,21(35):13334-13344. |
| APA | Li GG,Geng DL,Shang MM,Peng C,Cheng ZY,&Lin J.(2011).Tunable luminescence of Ce(3+)/Mn(2+)-coactivated Ca(2)Gd(8)(SiO(4))(6)O(2) through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors.journal of materials chemistry,21(35),13334-13344. |
| MLA | Li GG,et al."Tunable luminescence of Ce(3+)/Mn(2+)-coactivated Ca(2)Gd(8)(SiO(4))(6)O(2) through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors".journal of materials chemistry 21.35(2011):13334-13344. |
入库方式： OAI收割
来源：长春应用化学研究所
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