Synthesis, crystal structure, and magnetic properties of a phenoxo-bridged dinuclear nickel(II) complex
文献类型：期刊论文
| 作者 | Ke HS ; Zhao L ; Tang JK |
| 刊名 | journal of coordination chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 64期号:11页码:2020-2027 |
| 关键词 | ALKOXO BIS((N N-DIMETHYLFORMAMIDE) UTEROFERRIN TRINUCLEAR ZINC(II) LIGANDS DONORS |
| ISSN号 | 0095-8972 |
| 通讯作者 | tang jk |
| 中文摘要 | a new dinuclear nickel complex, [ni(2)(ii)(h(1.5)l)(2)](clo(4)) center dot 2ch(3)oh center dot h(2)o (1) (h(3)l 1,3-bis(salicylamino)-2-propanol), was synthesized and characterized by single-crystal x-ray diffraction, ir spectra, elemental analysis, and magnetic measurements. in contrast to commonly observed alcoholic oxygen bridges in previously reported dinuclear complexes, single-crystal x-ray studies reveal that the h(3)l is highly distorted and links two ni(ii) through the phenoxo oxygens of the ligands forming a [ni(2)o(2)] core. the remarkable distortion of the ligand brings the two non-bridging phenol groups from different ligands close to share one hydrogen, keeping charge neutrality of the complex. magnetic studies indicate that an overall antiferromagnetic interaction is operative between the metal centers. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000291543400016 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44980]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ke HS,Zhao L,Tang JK. Synthesis, crystal structure, and magnetic properties of a phenoxo-bridged dinuclear nickel(II) complex[J]. journal of coordination chemistry,2011,64(11):2020-2027. |
| APA | Ke HS,Zhao L,&Tang JK.(2011).Synthesis, crystal structure, and magnetic properties of a phenoxo-bridged dinuclear nickel(II) complex.journal of coordination chemistry,64(11),2020-2027. |
| MLA | Ke HS,et al."Synthesis, crystal structure, and magnetic properties of a phenoxo-bridged dinuclear nickel(II) complex".journal of coordination chemistry 64.11(2011):2020-2027. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。