A precursor strategy for the synthesis of low band-gap polymers: an efficient route to a series of near-infrared electrochromic polymers
文献类型：期刊论文
| 作者 | Qian G ; Abu H ; Wang ZY |
| 刊名 | journal of materials chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 21期号:21页码:7678-7685 |
| 关键词 | LIGHT-EMITTING-DIODES HETEROJUNCTION SOLAR-CELLS SEMICONDUCTING POLYMER CONJUGATED POLYMERS CHROMOPHORES GREEN BLUE ELECTROLUMINESCENCE PERFORMANCE DEVICES |
| ISSN号 | 0959-9428 |
| 通讯作者 | wang zy |
| 中文摘要 | a precursor strategy for the synthesis and screening of a series of conjugated donor-acceptor polymers is demonstrated by successful preparation of low band-gap polymers (p2-p5) containing triphenylamine as an electron donor and several heterocycles as acceptors, such as [1,2,5]thiadiazolo [ 3,4-g]quinoxaline, [1,2,5]thiadiazolo[3,4-i]dibenzo[a,c]phenazine, benzo[1,2-c:4,5-c']bis([1,2,5] thiadiazole), and selenadiazole[3,4-f]benzo[c][1,2,5] hiadiazole, that are transformed from a single reactive polymer (p1). polymers p2-p5 have the band gap of 1.71-1.29 ev and show the absorption and emission in the near infrared (nir) spectral region. all the polymers are also nir electrochromic. in particular, polymer p3 is electrochemically switchable between leaf-like green coloring and near-infrared absorbing states with an efficiency of 479 cm(2) c(-1) at 1310 nm or 232 cm(2) c(-1) at 1550 nm, making it potentially useful for electrically switchable day-to-night camouflage applications. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000290670000022 |
| 公开日期 | 2012-06-11 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/44990]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qian G,Abu H,Wang ZY. A precursor strategy for the synthesis of low band-gap polymers: an efficient route to a series of near-infrared electrochromic polymers[J]. journal of materials chemistry,2011,21(21):7678-7685. |
| APA | Qian G,Abu H,&Wang ZY.(2011).A precursor strategy for the synthesis of low band-gap polymers: an efficient route to a series of near-infrared electrochromic polymers.journal of materials chemistry,21(21),7678-7685. |
| MLA | Qian G,et al."A precursor strategy for the synthesis of low band-gap polymers: an efficient route to a series of near-infrared electrochromic polymers".journal of materials chemistry 21.21(2011):7678-7685. |
入库方式： OAI收割
来源：长春应用化学研究所
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