Interfacial Behavior of Cyanex 272 and Mass Transfer Kinetics of Ytterbium Using the Constant Interfacial Area Cell
文献类型:期刊论文
作者 | Xiong Y ; Wang WW ; Gao JQ ; Meng SL ; Li DQ ; Wu DB |
刊名 | separation science and technology
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出版日期 | 2011 |
卷号 | 46期号:6页码:959-964 |
关键词 | BIS(2 4 EXTRACTION 4-TRIMETHYLPENTYL) PHOSPHINIC ACID MECHANISM TENSION SEPARATION MEDIA WATER |
ISSN号 | 0149-6395 |
通讯作者 | li dq |
中文摘要 | the interfacial behavior of cyanex 272 has been investigated using the du nouy ring method. different adsorption isotherms such as the gibbs and szyszkowski isotherms have been found as fitting well to the experimental data. the values of interfacial excess at the saturated interface increase in the following order: n-heptanecyclohexaneccl4toluenebenzenechloroform, explained according to the stronger solution effect of aromatic hydrocarbon. the effects of temperature, acidity, and ionic strength of the aqueous phase on the interfacial activity of cyanex 272 are also examined and explained in detail. moreover, the reaction orders against cyanex 272 predicted from the interfacial tension isotherms are in agreement with the order determined experimentally, which suggests that the interfacial activity of cyanex 272 can provide enough strong evidence quantitatively supporting the interfacial mechanism. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000289583400009 |
公开日期 | 2012-06-12 |
源URL | [http://ir.ciac.jl.cn/handle/322003/45102] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Xiong Y,Wang WW,Gao JQ,et al. Interfacial Behavior of Cyanex 272 and Mass Transfer Kinetics of Ytterbium Using the Constant Interfacial Area Cell[J]. separation science and technology,2011,46(6):959-964. |
APA | Xiong Y,Wang WW,Gao JQ,Meng SL,Li DQ,&Wu DB.(2011).Interfacial Behavior of Cyanex 272 and Mass Transfer Kinetics of Ytterbium Using the Constant Interfacial Area Cell.separation science and technology,46(6),959-964. |
MLA | Xiong Y,et al."Interfacial Behavior of Cyanex 272 and Mass Transfer Kinetics of Ytterbium Using the Constant Interfacial Area Cell".separation science and technology 46.6(2011):959-964. |
入库方式: OAI收割
来源:长春应用化学研究所
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