(Zn, Mg)(2)GeO(4):Mn(2+) submicrorods as promising green phosphors for field emission displays: hydrothermal synthesis and luminescence properties
文献类型:期刊论文
作者 | Shang MM ; Li GG ; Yang DM ; Kang XJ ; Peng C ; Cheng ZY ; Lin J |
刊名 | dalton transactions
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出版日期 | 2011 |
卷号 | 40期号:37页码:9379-9387 |
关键词 | ELECTROLUMINESCENT DEVICES ZNGA2O4 PHOSPHOR ELECTROSPINNING PREPARATION ZN2GEO4-MN PHOSPHOR OPTICAL-PROPERTIES DIFFERENT SHAPES THIN-FILMS PHOTOLUMINESCENCE NANOCRYSTALS CATHODOLUMINESCENCE |
ISSN号 | 1477-9226 |
通讯作者 | shang mm |
中文摘要 | (zn(1-x-y)mg(y))(2)geo(4): xmn(2+) (y = 0-0.30; x = 0-0.035) phosphors with uniform submicrorod morphology were synthesized through a facile hydrothermal process. x-ray diffraction (xrd), field emission scanning electron microscopy (fe-sem), photoluminescence (pl), and cathodoluminescence (cl) spectroscopy were utilized to characterize the samples. sem and tem images indicate that zn(2)geo(4):mn(2+) samples consist of submicrorods with lengths around 1-2 mu m and diameters around 200-250 nm, respectively. the possible formation mechanism for zn(2)geo(4) submicrorods has been presented. pl and cl spectroscopic characterizations show that pure zn(2)geo(4) sample shows a blue emission due to defects, while zn(2)geo(4):mn(2+) phosphors exhibit a green emission corresponding to the characteristic transition of mn(2+) ((4)t(1) -> (6)a(1)) under the excitation of uv and low-voltage electron beam. compared with zn(2)geo(4):mn(2+) sample prepared by solid-state reaction, zn(2)geo(4):mn(2+) phosphors obtained by hydrothermal process followed by high temperature annealing show better luminescence properties. in addition, codoping mg(2+) ions into the lattice to substitute for zn(2+) ions can enhance both the pl and cl intensity of zn(2)geo(4):mn(2+) phosphors. furthermore, zn(2)geo(4):mn(2+) phosphors exhibit more saturated green emission than the commercial feds phosphor zno:zn, and it is expected that these phosphors are promising for application in field-emission displays. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2012-06-12 |
源URL | [http://ir.ciac.jl.cn/handle/322003/45108] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Shang MM,Li GG,Yang DM,et al. (Zn, Mg)(2)GeO(4):Mn(2+) submicrorods as promising green phosphors for field emission displays: hydrothermal synthesis and luminescence properties[J]. dalton transactions,2011,40(37):9379-9387. |
APA | Shang MM.,Li GG.,Yang DM.,Kang XJ.,Peng C.,...&Lin J.(2011).(Zn, Mg)(2)GeO(4):Mn(2+) submicrorods as promising green phosphors for field emission displays: hydrothermal synthesis and luminescence properties.dalton transactions,40(37),9379-9387. |
MLA | Shang MM,et al."(Zn, Mg)(2)GeO(4):Mn(2+) submicrorods as promising green phosphors for field emission displays: hydrothermal synthesis and luminescence properties".dalton transactions 40.37(2011):9379-9387. |
入库方式: OAI收割
来源:长春应用化学研究所
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