Chiral Biscarboline N,N'-Dioxide Derivatives: Highly Enantioselective Addition of Allyltrichlorosilane to Aldehydes
文献类型：期刊论文
| 作者 | Bai, Bing1,2; Shen, Lan1,2; Ren, Jie1; Zhu, Hua Jie1,3 |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2012-02-01 |
| 卷号 | 354期号:2-3页码:354-358 |
| 关键词 | allylation asymmetric catalysis 1 1'-biscarboline N N'-dioxides organocatalysts |
| ISSN号 | 1615-4150 |
| 通讯作者 | Zhu, HJ (reprint author), Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Lanhei Rd 132, Kunming 650204, Peoples R China, hjzhu@mail.kib.ac.cn |
| 英文摘要 | The allylation of aromatic and aliphatic aldehydes with allyltrichlorosilanes has been catalyzed with a new Lewis base organocatalyst, 1,1'-biscarboline N,N'-dioxide with high enantioselectivities of up to 99% for 4-methoxybenzaldehyde and 97% ee for cycloformaldehyde, respectively. In total, 13 heteroaryl and aliphatic aldehydes were tested. |
| 学科主题 | Chemistry, Applied; Chemistry, Organic |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | PYRIDINE N-OXIDES ; ATROPOISOMERIC BIPYRIDINE N,N'-DIOXIDES ; CATALYTIC ASYMMETRIC ALLYLATION ; LEWIS-BASE ACTIVATION ; SILYL KETENE ACETALS ; AROMATIC-ALDEHYDES ; ABSOLUTE-CONFIGURATION ; TITANIUM TETRACHLORIDE ; EFFICIENT CATALYST ; OPTICAL ROTATIONS |
| 收录类别 | SCI ; IC ; CCR |
| 资助信息 | NSFC[30873141]; 973 program[2009CB522300]; Hebei University |
| 语种 | 英语 |
| WOS记录号 | WOS:000300448400013 |
| 公开日期 | 2012-06-07 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/10463]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Phytochem & Plant Resources W China, Kunming Inst Bot, Kunming 650204, Peoples R China 2.CAS, Grad Sch, Beijing 100049, Peoples R China 3.Hebei Univ, Key Lab Med Chem & Mol Diag, Minist Educ, Baoding 071002, Peoples R China |
| 推荐引用方式 GB/T 7714 | Bai, Bing,Shen, Lan,Ren, Jie,et al. Chiral Biscarboline N,N'-Dioxide Derivatives: Highly Enantioselective Addition of Allyltrichlorosilane to Aldehydes[J]. ADVANCED SYNTHESIS & CATALYSIS,2012,354(2-3):354-358. |
| APA | Bai, Bing,Shen, Lan,Ren, Jie,&Zhu, Hua Jie.(2012).Chiral Biscarboline N,N'-Dioxide Derivatives: Highly Enantioselective Addition of Allyltrichlorosilane to Aldehydes.ADVANCED SYNTHESIS & CATALYSIS,354(2-3),354-358. |
| MLA | Bai, Bing,et al."Chiral Biscarboline N,N'-Dioxide Derivatives: Highly Enantioselective Addition of Allyltrichlorosilane to Aldehydes".ADVANCED SYNTHESIS & CATALYSIS 354.2-3(2012):354-358. |
入库方式： OAI收割
来源：昆明植物研究所
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