Silanized Titanium Silicate (TS-1) Molecular Sieve for Promoting the Homogeneously Catalyzed Oxidation of Cyclohexane
文献类型：会议论文
| 作者 | Wang DQ ; Zhang YB ; Xiao DH ; Yang XG |
| 出版日期 | 2011 |
| 会议名称 | 6th international conference on environmental catalysis (6th icec) |
| 会议日期 | 2010-09-12 |
| 会议地点 | 北京 |
| 关键词 | 血液相容性 表面接枝聚合 聚丙烯无纺布 2-丙烯酰胺基-2-甲基丙磺酸 |
| 页码 | 723-726 |
| 通讯作者 | yang xg |
| 中文摘要 | the promoting effect of titanium silicate (ts-1) molecular sieve and silanized ts-1 (ts-1-s) on the homogeneous liquid oxidation of cyclohexane catalyzed by cobalt naphthenate (co-nap) with oxygen as oxidant was investigated. both ts-1 zeolites were efficient. promoters. the conversion of cyclohexane was 7.9% with a selectivity of 83.7% when it was catalyzed by co-nap/ts-1-s, and the reaction time was reduced to 130 min as compared to 300 min with co-nap as the catalyst. the adsorption of co-nap on ts-1-s, which transformed a. homogeneous reaction into a "quasi-heterogeneous" reaction, was the reason for the better catalytic performance. |
| 收录类别 | SCI收录期刊论文 |
| 会议录 | chinese journal of catalysis
 |
| 会议录出版者 | science china press, 16 donghuangchenggen north st, beijing 100717, peoples r china |
| 会议录出版地 | 北京 |
| 语种 | 中文 |
| ISSN号 | 0253-9837 |
| WOS记录号 | WOS:000291508200004 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/47514]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_会议论文 |
| 推荐引用方式 GB/T 7714 | Wang DQ,Zhang YB,Xiao DH,et al. Silanized Titanium Silicate (TS-1) Molecular Sieve for Promoting the Homogeneously Catalyzed Oxidation of Cyclohexane[C]. 见:6th international conference on environmental catalysis (6th icec). 北京. 2010-09-12. |
入库方式： OAI收割
来源：长春应用化学研究所
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