4-氯酚的辐射降解机理研究
文献类型：期刊论文
| 作者 | 汪世龙,朱大章,孙晓宇,李文哲,曾凯玲,倪亚明,王文锋,姚思德 |
| 刊名 | 辐射研究与辐射工艺学报
 |
| 出版日期 | 2005-04-30 |
| 期号 | 02 |
| 关键词 | 4-氯酚 降解机理 脉冲辐解 γ辐解 |
| 通讯作者 | 汪世龙 |
| 中文摘要 | Reactions of 4-chlorophenol, and other phenols, with eaq , ?H, ?N3 and ?OH in aqueous solutions were studied - by nano-second pulse radiolysis. The transient absorption spectra were attributed to determine the micro-reaction rate constants. It was found that the phenols were more easily oxidized by ?OH than reduced by eaq ; and pH value - and molecular structure of the phenols affected the rate constants of the reactions. In addition, γ-ray radiolysis of 4-chlorophenol aqueous solution was performed and the degradation products were analyzed with HPLC, GC-MS and other methods. It is concluded that the radiolysis technology alone is not efficient in terms of mineralization of the phenol and the presence of O2 and alkaline conditions can facilitate the mineralization process. |
| 收录类别 | CNKI |
| 公开日期 | 2012-07-04 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/9230]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2004-2010年 |
| 推荐引用方式 GB/T 7714 | 汪世龙,朱大章,孙晓宇,李文哲,曾凯玲,倪亚明,王文锋,姚思德. 4-氯酚的辐射降解机理研究[J]. 辐射研究与辐射工艺学报,2005(02). |
| APA | 汪世龙,朱大章,孙晓宇,李文哲,曾凯玲,倪亚明,王文锋,姚思德.(2005).4-氯酚的辐射降解机理研究.辐射研究与辐射工艺学报(02). |
| MLA | 汪世龙,朱大章,孙晓宇,李文哲,曾凯玲,倪亚明,王文锋,姚思德."4-氯酚的辐射降解机理研究".辐射研究与辐射工艺学报 .02(2005). |
入库方式： OAI收割
来源：上海应用物理研究所
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