A comparative study on the ionic liquid [bmim][BF4] and its solution with transient absorption spectroscopy
文献类型：期刊论文
| 作者 | Zhu, Guanglai（朱光来） ; Wu, Guozhong（吴国忠） ; Xu, Xinsheng ; Ji, Xuehan |
| 刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2011 |
| 卷号 | 82期号:1页码:74 |
| ISSN号 | 1386-1425 |
| 英文摘要 | A detailed study was explored to compare the transient absorption spectra of the neat 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) with its solution in water or acetonitrile. It was concluded that the excited triplet state (3)[bmim](+center dot) was produced after 266 nm laser irradiation, and then the neutral radical [bmim](center dot) and the cation radical [bmim](2+center dot) were formed through two possible paths. The transient absorption spectra of the neat [bmim][BF4] and its solution were similar but the reaction kinetics were different due to their different local structures such as dimeric or cluster. The energy transfer between excited [bmim][BF4]] and beta-carotene further affirmed the existence of (3)[bmim](+center dot). And the reaction that the hydrated electron captured by [bmim](+) to produce [bmim](center dot) in solution was observed. (C) 2011 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000295956500012 |
| 公开日期 | 2012-07-04 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/9449]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Zhu, Guanglai,Wu, Guozhong,Xu, Xinsheng,et al. A comparative study on the ionic liquid [bmim][BF4] and its solution with transient absorption spectroscopy[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2011,82(1):74. |
| APA | Zhu, Guanglai,Wu, Guozhong,Xu, Xinsheng,&Ji, Xuehan.(2011).A comparative study on the ionic liquid [bmim][BF4] and its solution with transient absorption spectroscopy.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,82(1),74. |
| MLA | Zhu, Guanglai,et al."A comparative study on the ionic liquid [bmim][BF4] and its solution with transient absorption spectroscopy".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 82.1(2011):74. |
入库方式： OAI收割
来源：上海应用物理研究所
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