Fluoride ion yield and absorption spectral analysis of irradiated imidazolium-based room-temperature ionic liquids
文献类型:期刊论文
作者 | Huang, Wei ; Chen, Shimou(陈仕谋) ; Liu, Yusheng ; Fu, Haiying(付海英) ; Wu, Guozhong(吴国忠) |
刊名 | RADIATION PHYSICS AND CHEMISTRY
![]() |
出版日期 | 2011 |
卷号 | 80期号:4页码:573 |
ISSN号 | 0969-806X |
英文摘要 | The radiation chemical yields of F ions (G(F(-)) values) were measured for a group of imidazolium-based room-temperature ionic liquids following (60)Co gamma ray irradiation. The G(F(-)) values of ionic liquids: hexafluorophosphate, bis[(trifluoromethyl)sulfonyl]imide, trifluoromethanesulfonate and tetrafluoroborate anions associated with 1-butyl-3-methylimidazolium cations were determined to be 0.227, 0.136, 0.101 and 0.008 mu mol J(-1), respectively. The G(F(-)) value is dependent on the F-X (X = B, P. etc.) bond energy and the anion structure and can be considered as an indicator of the radiation stability of fluorine-containing ionic liquids. In addition, as confirmed by UV-Vis absorption measurement, the radiolytic products with strong photoabsorption and color darkening depend on the structures of both the cation and the anion. (C) 2010 Elsevier Ltd. All rights reserved. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000287624600008 |
公开日期 | 2012-07-04 |
源URL | [http://ir.sinap.ac.cn/handle/331007/9513] ![]() |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
推荐引用方式 GB/T 7714 | Huang, Wei,Chen, Shimou,Liu, Yusheng,et al. Fluoride ion yield and absorption spectral analysis of irradiated imidazolium-based room-temperature ionic liquids[J]. RADIATION PHYSICS AND CHEMISTRY,2011,80(4):573. |
APA | Huang, Wei,Chen, Shimou,Liu, Yusheng,Fu, Haiying,&Wu, Guozhong.(2011).Fluoride ion yield and absorption spectral analysis of irradiated imidazolium-based room-temperature ionic liquids.RADIATION PHYSICS AND CHEMISTRY,80(4),573. |
MLA | Huang, Wei,et al."Fluoride ion yield and absorption spectral analysis of irradiated imidazolium-based room-temperature ionic liquids".RADIATION PHYSICS AND CHEMISTRY 80.4(2011):573. |
入库方式: OAI收割
来源:上海应用物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。