Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes
文献类型：期刊论文
| 作者 | Zhao, Guang-Jiu1; Yu, Fabiao1; Zhang, Ming-Xing1; Northrop, Brian H.2; Yang, Haibo2; Han, Ke-Li1; Stang, Peter J.2 |
| 刊名 | journal of physical chemistry a
 |
| 出版日期 | 2011-06-23 |
| 卷号 | 115期号:24页码:6390-6393 |
| ISSN号 | 待补充 |
| 产权排序 | 1,1 |
| 通讯作者 | 韩克利 |
| 中文摘要 | substituent effects on the intramolecular charge transfer and fluorescence of bimetallic platinum complexes |
| 英文摘要 | an investigation of a series of platinum-containing organometallic complexes for the study of fluorescence phenomena in organometallic chromophores controlled by the intrarnolecular charge transfer (ict) is presented in this work. we report steady-state and time-resolved spectroscopic experiments as well as quantum chemistry calculations to investigate the substituent effects on the ict and fluorescence emission. we demonstrate that the fluorescence maximum and lifetimes greatly depend on different substituents and the presence of bimetallic platinum donor. this work paves the way for an understanding of the fluorescence phenomena controlled by molecular ict characters of these kinds of platinum-containing organometallic complexes. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | supramolecular rectangle ; terpyridyl complexes ; coordination cages ; dimer complex ; photochemistry ; symmetry ; systems ; intermediate ; spectroscopy ; photophysics |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000291709400010 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115233]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA |
| 推荐引用方式 GB/T 7714 | Zhao, Guang-Jiu,Yu, Fabiao,Zhang, Ming-Xing,et al. Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes[J]. journal of physical chemistry a,2011,115(24):6390-6393. |
| APA | Zhao, Guang-Jiu.,Yu, Fabiao.,Zhang, Ming-Xing.,Northrop, Brian H..,Yang, Haibo.,...&Stang, Peter J..(2011).Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes.journal of physical chemistry a,115(24),6390-6393. |
| MLA | Zhao, Guang-Jiu,et al."Substituent Effects on the Intramolecular Charge Transfer and Fluorescence of Bimetallic Platinum Complexes".journal of physical chemistry a 115.24(2011):6390-6393. |
入库方式： OAI收割
来源：大连化学物理研究所
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