Ionic liquids as novel spectroscopic solvents for Eu(III)-containing complex
文献类型：期刊论文
| 作者 | Deng Yuefeng1,2; Zhao He1; Chen Ji1; Li Yimin2; Gong Faquan2; Han Xinmin2; Liu Wanfa2 |
| 刊名 | journal of rare earths
 |
| 出版日期 | 2011-10-01 |
| 卷号 | 29期号:10页码:915-919 |
| 关键词 | ionic liquids europium luminescence rare earths |
| ISSN号 | 待补充 |
| 产权排序 | 1,1 |
| 通讯作者 | 陈继 ; 刘万发 |
| 中文摘要 | ionic liquids as novel spectroscopic solvents for eu(iii)-containing complex |
| 英文摘要 | novel soft materials, eu(iii)-containing complex dissolved in [c(8)mim][x] (x=cl-, pf6- and tf2n-) ionic liquids, were synthesized. ft-ir and elementary analysis of complex proved that the molecular formula is [c(8)mim][eu(tta)(4)]. the complex and ionic liquids had high thermal stability according to tga. the photoluminescence spectra showed that the [c8mim][eu(tta) 4] exhibited typical red emission deriving from d-5(0)-f-7(2) transition. after dissolving the complex in [c(8)mim][x] (x=cl-, pf6- and tf2n-) ionic liquids, the luminescence intensity decreased in the following order: [c(8)mim][tf2n]approximate to[c(8)mim][pf6]>[c(8)mim][cl]. this was because tf2n- and pf6- anions had larger molecular volume and weaker coordination ability than cl-. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | luminescence |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000297028400002 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115399]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Chem Lasers, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng Yuefeng,Zhao He,Chen Ji,et al. Ionic liquids as novel spectroscopic solvents for Eu(III)-containing complex[J]. journal of rare earths,2011,29(10):915-919. |
| APA | Deng Yuefeng.,Zhao He.,Chen Ji.,Li Yimin.,Gong Faquan.,...&Liu Wanfa.(2011).Ionic liquids as novel spectroscopic solvents for Eu(III)-containing complex.journal of rare earths,29(10),915-919. |
| MLA | Deng Yuefeng,et al."Ionic liquids as novel spectroscopic solvents for Eu(III)-containing complex".journal of rare earths 29.10(2011):915-919. |
入库方式： OAI收割
来源：大连化学物理研究所
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