Improved hydrogen desorption properties of Co-doped Li2BNH6
文献类型：期刊论文
| 作者 | Zheng XueLi1,2; Wu GuoTao1; He Teng1; Chu HaiLiang1; Chen Hua2; Chen Ping1 |
| 刊名 | chinese science bulletin
 |
| 出版日期 | 2011-08-01 |
| 卷号 | 56期号:23页码:2481-2485 |
| 关键词 | lithium amide cobalt lithium borohydride hydrogen release |
| ISSN号 | 待补充 |
| 产权排序 | 2,1 |
| 通讯作者 | 吴国涛 |
| 中文摘要 | improved hydrogen desorption properties of co-doped li2bnh6 |
| 英文摘要 | the hydrogen desorption properties of li2bnh6 were improved by doping with cobalt. with the addition of cocl2 (7 wt%), more than 8 wt% of hydrogen was released from li2bnh6 at temperatures below 210a degrees c, which is approximately 90a degrees c lower than that of pristine li2bnh6. x-ray diffraction, fourier transform-infrared and raman characterizations revealed that the dehydrogenation was a stepwise process with the formation of intermediates li4bn3h10 and libh4 and final products of li3bn2 and lih. the introduction of co greatly accelerated the dehydrogenation of li4bn3h10. x-ray absorption near-edge structure measurements revealed that co and cob species formed during ball milling of cocl2 with libh4 and linh2, which may function as catalyst in the subsequent dehydrogenation. |
| WOS标题词 | science & technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | multidisciplinary sciences |
| 研究领域[WOS] | science & technology - other topics |
| 关键词[WOS] | ammonia-borane ; lithium borohydride ; crystal-structure ; storage materials ; libh4 ; system ; release ; complex ; lib0.33n0.67h2.67 ; nitrides |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000292928700012 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115418]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Inst Homogeneous Catalysis,Coll Chem, Chengdu 610064, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng XueLi,Wu GuoTao,He Teng,et al. Improved hydrogen desorption properties of Co-doped Li2BNH6[J]. chinese science bulletin,2011,56(23):2481-2485. |
| APA | Zheng XueLi,Wu GuoTao,He Teng,Chu HaiLiang,Chen Hua,&Chen Ping.(2011).Improved hydrogen desorption properties of Co-doped Li2BNH6.chinese science bulletin,56(23),2481-2485. |
| MLA | Zheng XueLi,et al."Improved hydrogen desorption properties of Co-doped Li2BNH6".chinese science bulletin 56.23(2011):2481-2485. |
入库方式： OAI收割
来源：大连化学物理研究所
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