Glycerol Hydrogenolysis over Co Catalysts Derived from a Layered Double Hydroxide Precursor
文献类型:期刊论文
作者 | Guo, Xiaohui; Li, Yong; Song, Wei; Shen, Wenjie |
刊名 | catalysis letters
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出版日期 | 2011-10-01 |
卷号 | 141期号:10页码:1458-1463 |
关键词 | Glycerol Hydrogenolysis 1 Layered double hydroxide Co catalyst 2-Propanediol |
ISSN号 | 待补充 |
产权排序 | 1,1 |
通讯作者 | 申文杰 |
中文摘要 | glycerol hydrogenolysis over co catalysts derived from a layered double hydroxide precursor |
英文摘要 | co catalysts, obtained from a layered double co-zn-al hydroxide, are highly active and stable towards the hydrogenolysis of glycerol to 1,2-propanediol (1,2-pdo) in aqueous media. the co-673 catalyst, containing a coo species, provided a glycerol conversion of 67.7% and a 1,2-pdo selectivity of 50.5%. the co-873 catalyst comprising 16 nm co nanoparticles gave a glycerol conversion of 70.6% and a 1,2-pdo selectivity of 57.8%. it was revealed that the coo species in the co-673 catalyst was readily converted to 50 nm co particles under the glycerol hydrogenolysis conditions. the co catalysts maintained a stable size and phase in recycling tests. |
WOS标题词 | science & technology ; physical sciences |
学科主题 | 物理化学 |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | cu-zno catalysts ; selective hydrogenolysis ; structural-properties ; reaction-mechanism ; propylene-glycol ; supported ru ; 1,2-propanediol ; conversion ; cobalt ; oxides |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000295519500008 |
公开日期 | 2012-07-09 |
源URL | [http://159.226.238.44/handle/321008/115462] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Guo, Xiaohui,Li, Yong,Song, Wei,et al. Glycerol Hydrogenolysis over Co Catalysts Derived from a Layered Double Hydroxide Precursor[J]. catalysis letters,2011,141(10):1458-1463. |
APA | Guo, Xiaohui,Li, Yong,Song, Wei,&Shen, Wenjie.(2011).Glycerol Hydrogenolysis over Co Catalysts Derived from a Layered Double Hydroxide Precursor.catalysis letters,141(10),1458-1463. |
MLA | Guo, Xiaohui,et al."Glycerol Hydrogenolysis over Co Catalysts Derived from a Layered Double Hydroxide Precursor".catalysis letters 141.10(2011):1458-1463. |
入库方式: OAI收割
来源:大连化学物理研究所
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