Mesoporous SBA-15 materials modified with PW or W active species as catalysts for the epoxidation of olefins with H2O2
文献类型：期刊论文
| 作者 | Zhang, Aiping1,2; Zhang, Yi1; Wang, Puguang3; Li, Jun1; Lv, Ying1; Gao, Shuang1 |
| 刊名 | research on chemical intermediates
 |
| 出版日期 | 2011-10-01 |
| 卷号 | 37期号:8页码:975-984 |
| 关键词 | Epoxidation Hybrid materials Hydrogen peroxide Immobilization |
| ISSN号 | 待补充 |
| 产权排序 | 1,1 |
| 通讯作者 | 高爽 |
| 中文摘要 | mesoporous sba-15 materials modified with pw or w active species as catalysts for the epoxidation of olefins with h2o2 |
| 英文摘要 | five catalysts containing pw or w active species that anchored onto aminosilylated mesoporous silica sba-15 by a post-grafting route were prepared and the resulting pw or w/aptes/sba-15 hybrid materials were characterized by xrd, n-2 adsorption/desorption, surface area analysis, tem, ft-ir, and icp (inductively coupled plasma atomic emission spectroscopy). the names of these catalysts have been abbreviated as sba-15m-a, sba-15m-b, sba-15m-c, sba-15m-d, and sba-15m-e according to the different active species. the pw or w active species were highly dispersed in the channels of the modified mesoporous materials. the interaction between pw or w species and amino groups grafted on the channel surface of sba-15 led to the immobilization of pw or w species. their catalytic activity in the epoxidation of cyclooctene with h2o2 as oxidant was investigated. among them, sba-15m-a showed the best performance, with 98.9% conversion and 98.4% selectivity. the catalyst could be reused for six times with a little decrease in activity. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | aqueous hydrogen-peroxide ; phase-transfer catalysis ; efficient epoxidation ; oxidant ; alkenes ; silica ; peroxotungstate ; propylene ; complex ; acid |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000295140200014 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115519]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Shanxi Yanchang Petr Grp Co Ltd, Xian 710075, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Aiping,Zhang, Yi,Wang, Puguang,et al. Mesoporous SBA-15 materials modified with PW or W active species as catalysts for the epoxidation of olefins with H2O2[J]. research on chemical intermediates,2011,37(8):975-984. |
| APA | Zhang, Aiping,Zhang, Yi,Wang, Puguang,Li, Jun,Lv, Ying,&Gao, Shuang.(2011).Mesoporous SBA-15 materials modified with PW or W active species as catalysts for the epoxidation of olefins with H2O2.research on chemical intermediates,37(8),975-984. |
| MLA | Zhang, Aiping,et al."Mesoporous SBA-15 materials modified with PW or W active species as catalysts for the epoxidation of olefins with H2O2".research on chemical intermediates 37.8(2011):975-984. |
入库方式： OAI收割
来源：大连化学物理研究所
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