An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures
文献类型：期刊论文
| 作者 | Zhang, Zehui1,3,4; Liu, Wujun1; Xie, Haibo1,2; Zhao, Zongbao K.1,2 |
| 刊名 | molecules
 |
| 出版日期 | 2011-10-01 |
| 卷号 | 16期号:10页码:8463-8474 |
| 关键词 | side reaction HMF ionic liquids 1-butyl-2-(5 '-methyl-2 '-furoyl)imidazole |
| ISSN号 | 1420-3049 |
| 产权排序 | 1,1 |
| 通讯作者 | 谢海波 ; 赵宗保 |
| 中文摘要 | an unexpected reaction between 5-hydroxymethylfurfural and imidazolium-based ionic liquids at high temperatures |
| 英文摘要 | a new compound was detected during the production of 5-hydroxymethylfurfural (hmf) from glucose and cellulose in the ionic liquid 1-butyl-3-methylimidazolium chloride ([bmim]cl) at high temperatures. further experiments found that it was derived from the reaction of hmf with [bmim]cl. the structure of new compound was established as 1-butyl-2-(5'-methyl-2'-furoyl) imidazole (bmi) based on nuclear magnetic resonance and mass spectrometry analysis, and a possible mechanism for its formation was proposed. reactions of hmf with other imidazolium-based ionic liquids were performed to check the formation of bmi. our results provided new insights in terms of side reactions between hmf and imidazolium-based ionic liquids, which should be valuable for designing better processes for the production of furans using biomass and related materials. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | physical-properties ; solvents ; solubility ; conversion ; catalysis ; chemistry ; salts |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000296973000024 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115575]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.S Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Peoples R China 4.S Cent Univ Nationalities, Minist Educ, Coll Chem & Mat Sci, Wuhan 430074, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zehui,Liu, Wujun,Xie, Haibo,et al. An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures[J]. molecules,2011,16(10):8463-8474. |
| APA | Zhang, Zehui,Liu, Wujun,Xie, Haibo,&Zhao, Zongbao K..(2011).An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures.molecules,16(10),8463-8474. |
| MLA | Zhang, Zehui,et al."An Unexpected Reaction between 5-Hydroxymethylfurfural and Imidazolium-Based Ionic Liquids at High Temperatures".molecules 16.10(2011):8463-8474. |
入库方式： OAI收割
来源：大连化学物理研究所
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