Carbon-supported Pd-Pt cathode electrocatalysts for proton exchange membrane fuel cells
文献类型：期刊论文
| 作者 | Tang, Yongfu1,2; Zhang, Huamin1; Zhong, Hexiang1; Xu, Ting1,2; Jin, Hong1,2 |
| 刊名 | journal of power sources
 |
| 出版日期 | 2011-04-01 |
| 卷号 | 196期号:7页码:3523-3529 |
| 关键词 | Proton exchange membrane fuel cells Oxygen reduction reaction Carbon-supported Pd-Pt alloy Low-platinum electrocatalyst |
| ISSN号 | 待补充 |
| 产权排序 | 1,1 |
| 通讯作者 | 张华民 |
| 中文摘要 | carbon-supported pd-pt cathode electrocatalysts for proton exchange membrane fuel cells |
| 英文摘要 | a series of carbon-supported pd-pt alloy (pd-pt/c) catalysts for oxygen reduction reaction (orr) with low-platinum content are synthesized via a modified sodium borohydride reduction method. the structure of as-prepared catalysts is characterized by powder x-ray diffraction (xrd) and transmission electron microscope (tem) measurements. the prepared pd-pt/c catalysts with alloy form show face-centeredcubic (fcc) structure. the metal particles of pd-pt/c catalysts with mean size of around 4-5 nm are uniformly dispersed on the carbon support. the electrocatalytic activities for orr of these catalysts are investigated by rotating disk electrode (rde), cyclic voltammetry (cv), single cell measurements and electrochemical impedance spectra (eis) measurements. the results suggest that the electrocatalytic activities of pd-pt/c catalysts with low platinum are comparable to that of the commercial pt/c with the same metal loading. the maximum power density of mea with a pd-pt/c catalyst, the pd/pt mass ratio of which is 7:3, is about 1040 mw cm(-2). (c) 2010 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | oxygen reduction reaction ; phosphoric-acid ; catalytic-activity ; surface ; nanoparticles ; platinum ; alloys ; oxidation ; pemfc |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000289325000019 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115689]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab PEMFC Key Mat & Technol, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Yongfu,Zhang, Huamin,Zhong, Hexiang,et al. Carbon-supported Pd-Pt cathode electrocatalysts for proton exchange membrane fuel cells[J]. journal of power sources,2011,196(7):3523-3529. |
| APA | Tang, Yongfu,Zhang, Huamin,Zhong, Hexiang,Xu, Ting,&Jin, Hong.(2011).Carbon-supported Pd-Pt cathode electrocatalysts for proton exchange membrane fuel cells.journal of power sources,196(7),3523-3529. |
| MLA | Tang, Yongfu,et al."Carbon-supported Pd-Pt cathode electrocatalysts for proton exchange membrane fuel cells".journal of power sources 196.7(2011):3523-3529. |
入库方式： OAI收割
来源：大连化学物理研究所
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