Beyond the Limits of X-ray Powder Diffraction: Description of the Nonperiodic Subnetworks in Aluminophosphate-Cloverite by NMR Crystallography
文献类型：期刊论文
| 作者 | Martineau, Charlotte1; Bouchevreau, Boris1; Tian, Zhijian2; Lohmeier, Sven-Jare3; Behrens, Peter3; Taulelle, Francis1 |
| 刊名 | chemistry of materials
 |
| 出版日期 | 2011-11-08 |
| 卷号 | 23期号:21页码:4799-4809 |
| 关键词 | NMR crystallography generalized crystallography cloverite fluorinated aluminophosphate high-resolution NMR 2D correlation |
| ISSN号 | 待补充 |
| 产权排序 | 2,3 |
| 通讯作者 | martineau ; charlotte |
| 中文摘要 | beyond the limits of x-ray powder diffraction: description of the nonperiodic subnetworks in aluminophosphate-cloverite by nmr crystallography |
| 英文摘要 | nmr crystallography of the fluorinated aluminophosphate cloverite is presented, with an emphasis on the description of the nonperiodic part of the compound, i.e., the fluorine and organic subnetworks, which are very difficult to access by usual x-ray powder diffraction methods. multinuclear high-resolution 1d al-27 and p-31 nmr support the main cloverite-type topological features previously proposed for aluminum cloverite from powder x-ray diffraction. spatial proximities are extracted from the 2d p-31-p-31 and al-27-p-31 nmr spectra, allowing a full assignment of the p-31 and al-27 resonances to the corresponding phosphorus and aluminum sites in the structure. to go further into the description of the main periodic framework, c-13, n-15, and h-1 1d and h-1-h-1 and h-1-p-31 2d nmr measurements are employed, allowing the characterization and selective locations of the two costructural-directing agents in the pores and channels of the framework. the nonperiodic fluorine subnetwork is described by means of f-19-x (x = al-27 and p-31) 2d nmr experiments. two kinds of fluorine atoms are distinguished: f- ions trapped in d4r units and f atoms covalently bonded to terminal al or p atoms and which interrupt the alpo network. through the example of aluminum cloverite, we show that, despite the considerable complexity of such systems, an extremely detailed structural model can be obtained, including the simple rules that allow the description of the nonperiodic subnetworks that tailor the structure and properties of a compound, by coupling powder x-ray diffraction and high-resolution nmr data in a generalized crystallography approach. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; materials science |
| 关键词[WOS] | gallophosphate molecular-sieve ; crystalline inorganic solids ; nuclear-magnetic-resonance ; integer quadrupolar nuclei ; mas nmr ; generalized crystallography ; spin locking ; magic-angle ; hetcor nmr ; resolution |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000296304100023 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115722]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Versailles, CNRS, Tectospin Inst Lavoisier Versailles, UMR 8180, F-78035 Versailles, France 2.Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Leibniz Univ Hannover, Inst Anorgan Chem, D-30167 Hannover, Germany |
| 推荐引用方式 GB/T 7714 | Martineau, Charlotte,Bouchevreau, Boris,Tian, Zhijian,et al. Beyond the Limits of X-ray Powder Diffraction: Description of the Nonperiodic Subnetworks in Aluminophosphate-Cloverite by NMR Crystallography[J]. chemistry of materials,2011,23(21):4799-4809. |
| APA | Martineau, Charlotte,Bouchevreau, Boris,Tian, Zhijian,Lohmeier, Sven-Jare,Behrens, Peter,&Taulelle, Francis.(2011).Beyond the Limits of X-ray Powder Diffraction: Description of the Nonperiodic Subnetworks in Aluminophosphate-Cloverite by NMR Crystallography.chemistry of materials,23(21),4799-4809. |
| MLA | Martineau, Charlotte,et al."Beyond the Limits of X-ray Powder Diffraction: Description of the Nonperiodic Subnetworks in Aluminophosphate-Cloverite by NMR Crystallography".chemistry of materials 23.21(2011):4799-4809. |
入库方式： OAI收割
来源：大连化学物理研究所
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