New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation
文献类型:期刊论文
作者 | Han, Mei-Ling1,2; Hu, Xiang-Ping1; Huang, Jia-Di1; Chen, Li-Gong2; Zheng, Zhuo1 |
刊名 | tetrahedron-asymmetry |
出版日期 | 2011-01-31 |
卷号 | 22期号:2页码:222-225 |
ISSN号 | 待补充 |
通讯作者 | 胡向平 |
产权排序 | 2,1 |
中文摘要 | new chiral amino alcohol ligands derived from 1-phenylethylamine for efficient ru-catalyzed asymmetric transfer hydrogenation |
英文摘要 | a series of chiral amino alcohols have been prepared from cheap and readily available (s)-1-phenylethylamine through a one-step transformation. the ability of these newly developed amino alcohols as chiral ligands was evaluated in the ru-catalyzed asymmetric transfer hydrogenation of aromatic alkyl ketones, providing chiral secondary alcohols with good to excellent conversions (71-100%) and moderate to good enantioselectivities (67-95% ee). the results also showed that the structure of these amino alcohols has a significant influence on the conversion and enantioselectivity. (c) 2011 elsevier ltd. all rights reserved. |
学科主题 | 物理化学 |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, inorganic & nuclear ; chemistry, organic ; chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | alcohol)-catalyzed transfer hydrogenation ; aromatic ketones ; enantioselectivity ; complexes ; origin |
收录类别 | SCI ; IC ; CCR |
语种 | 英语 |
WOS记录号 | WOS:000288890800016 |
公开日期 | 2012-07-09 |
源URL | [http://159.226.238.44/handle/321008/115728] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China 2.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China |
推荐引用方式 GB/T 7714 | Han, Mei-Ling,Hu, Xiang-Ping,Huang, Jia-Di,et al. New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation[J]. tetrahedron-asymmetry,2011,22(2):222-225. |
APA | Han, Mei-Ling,Hu, Xiang-Ping,Huang, Jia-Di,Chen, Li-Gong,&Zheng, Zhuo.(2011).New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation.tetrahedron-asymmetry,22(2),222-225. |
MLA | Han, Mei-Ling,et al."New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation".tetrahedron-asymmetry 22.2(2011):222-225. |
入库方式: OAI收割
来源:大连化学物理研究所
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