中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation

文献类型:期刊论文

作者Han, Mei-Ling1,2; Hu, Xiang-Ping1; Huang, Jia-Di1; Chen, Li-Gong2; Zheng, Zhuo1
刊名tetrahedron-asymmetry
出版日期2011-01-31
卷号22期号:2页码:222-225
ISSN号待补充
通讯作者胡向平
产权排序2,1
中文摘要new chiral amino alcohol ligands derived from 1-phenylethylamine for efficient ru-catalyzed asymmetric transfer hydrogenation
英文摘要a series of chiral amino alcohols have been prepared from cheap and readily available (s)-1-phenylethylamine through a one-step transformation. the ability of these newly developed amino alcohols as chiral ligands was evaluated in the ru-catalyzed asymmetric transfer hydrogenation of aromatic alkyl ketones, providing chiral secondary alcohols with good to excellent conversions (71-100%) and moderate to good enantioselectivities (67-95% ee). the results also showed that the structure of these amino alcohols has a significant influence on the conversion and enantioselectivity. (c) 2011 elsevier ltd. all rights reserved.
学科主题物理化学
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, inorganic & nuclear ; chemistry, organic ; chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]alcohol)-catalyzed transfer hydrogenation ; aromatic ketones ; enantioselectivity ; complexes ; origin
收录类别SCI ; IC ; CCR
语种英语
WOS记录号WOS:000288890800016
公开日期2012-07-09
源URL[http://159.226.238.44/handle/321008/115728]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China
2.Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
推荐引用方式
GB/T 7714
Han, Mei-Ling,Hu, Xiang-Ping,Huang, Jia-Di,et al. New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation[J]. tetrahedron-asymmetry,2011,22(2):222-225.
APA Han, Mei-Ling,Hu, Xiang-Ping,Huang, Jia-Di,Chen, Li-Gong,&Zheng, Zhuo.(2011).New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation.tetrahedron-asymmetry,22(2),222-225.
MLA Han, Mei-Ling,et al."New chiral amino alcohol ligands derived from 1-phenylethylamine for efficient Ru-catalyzed asymmetric transfer hydrogenation".tetrahedron-asymmetry 22.2(2011):222-225.

入库方式: OAI收割

来源:大连化学物理研究所

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