Poly(vinylidene fluoride) based anion conductive ionomer as a catalyst binder for application in anion exchange membrane fuel cell
文献类型：期刊论文
| 作者 | Zhang, Fengxiang; Zhang, Huamin; Qu, Chao; Ren, Junxia |
| 刊名 | journal of power sources
 |
| 出版日期 | 2011-03-15 |
| 卷号 | 196期号:6页码:3099-3103 |
| 关键词 | Anion conductive ionomer Poly(vinylidene fluoride) Fuel cell Power density |
| ISSN号 | 待补充 |
| 产权排序 | 1,1 |
| 通讯作者 | 张凤祥 ; 张华民 |
| 中文摘要 | poly(vinylidene fluoride) based anion conductive ionomer as a catalyst binder for application in anion exchange membrane fuel cell |
| 英文摘要 | an anion conductive polymeric ionomer incorporated into the electrodes of an anion exchange membrane fuel cell (aemfc) can help to enhance anion transport in the catalyst layer of electrode, and thus improve the catalyst efficiency and performance of aemfc. in this work, we report the synthesis and properties of a new type of anion conductive ionomer, which is synthesized by grafting of poly(vinylidene fluoride), or pvdf with poly(vinylbenzyltrimethylammonium chloride) via atom transfer radical polymerization. the ionomer obtained shows improved hydrophilicity relative to pristine pvdf, and exhibits an ion exchange capacity of 1.59 mmol g(-1). when used in a direct hydrazine hydrate fuel cell (dhfc) as a catalyst binder, the synthesized ionomer imparts the dhfc a significantly improved power density, which is 5-10 fold as much as that of the cells without using such ionomer. the method developed here for anion exchange ionomer synthesis is facile, green and does not involve the use of carcinogenic chemicals such as chloromethylmethylether and trimethylamine, which are often used for conventional anion exchange membrane or ionomer synthesis. (c) 2010 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | butyl acrylate ; alkaline ; performance ; methacrylate ; copolymers ; hydroxide ; atrp |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287058800020 |
| 公开日期 | 2012-07-09 |
| 源URL | [http://159.226.238.44/handle/321008/115730]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Lab Fuel Cell Key Mat & Components, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Fengxiang,Zhang, Huamin,Qu, Chao,et al. Poly(vinylidene fluoride) based anion conductive ionomer as a catalyst binder for application in anion exchange membrane fuel cell[J]. journal of power sources,2011,196(6):3099-3103. |
| APA | Zhang, Fengxiang,Zhang, Huamin,Qu, Chao,&Ren, Junxia.(2011).Poly(vinylidene fluoride) based anion conductive ionomer as a catalyst binder for application in anion exchange membrane fuel cell.journal of power sources,196(6),3099-3103. |
| MLA | Zhang, Fengxiang,et al."Poly(vinylidene fluoride) based anion conductive ionomer as a catalyst binder for application in anion exchange membrane fuel cell".journal of power sources 196.6(2011):3099-3103. |
入库方式： OAI收割
来源：大连化学物理研究所
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